Estimation Of Standard Enthalpies Of Formation Of Inorganic And Organometallic Compounds. Ii

Correlations between the standard enthalpies of formation of organometallic and inorganic compounds MXnLm and of ligands LH or LHm, both in their standard reference states, are examined in detail and illustrated with examples. They provide a simple method of predicting new values and assessing experimental data. © 1989.3613319334Dias, Martinho Simões, Teixeira, Airoldi, Chagas, (1987) J. Organomet. Chem., 335, p. 71Pedley, Rylance, (1977) Sussex-N.P.L. Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, , University of Sussex, BrightonSteele, (1983) J. Chem. Thermodyn., 15, p. 595Only crystalline complexes were considered in ref. 1, but the method also applies to liquids (see examples below). Thus the plots refer to MXnLm and LH, both in their standard reference statesSee ref. 1 and refs. cited thereinA.R. Dias, M.E. Minas da Piedade, and J.A. Martinho Simões, to be publishedA.R. Dias and J.A. Martinho Simões, Polyhedron, in pressBruno, Marks, Morss, (1983) J. Am. Chem. Soc., 105, p. 6824Bruno, Stecher, Morss, Sonnenberger, Marks, (1986) J. Am. Chem. Soc., 108, p. 7275Smith, Suzuki, Sonnenberger, Day, Marks, (1986) Organometallics, 5, p. 549ΔH°(14) = 39.8 ±15.2 kJ mol−1 when the enthalpy of formation of liquid LH2 = 2-C4H8 is used. However, the standard reference state of this compound is a gasBruno, Smith, Marks, Fair, Schultz, Williams, Carbon-hydrogen activation mechanisms and regioselectivity in the cyclometalation reactions of bis(pentamethylcyclopentadienyl)thorium dialkyl complexes (1988) Journal of the American Chemical Society, 108, p. 40Bradley, Hillyer, (1966) Trans. Faraday Soc., 62, p. 2367Bradley, Hillyer, (1966) Trans. Faraday Soc., 62, p. 2374Tel'noi, Rabinovich, Kozyrkin, Salamatin, Kir'yanov, (1972) Dokl. Akad. Nauk S.S.S.R., 205, p. 364Tel'noi, Rabinovich, Thermochemistry of Organic Compounds of Transition Metals (1977) Russian Chemical Reviews, 46, p. 1337Hubert-Pfalzgraf, Postel, Riess, (1987) Comprehensive Coordination Chemistry, 3. , G. Wilkinson, R.D. Gillard, J.A. McCleverty, Pergamon, Oxford, chapter 34Pilcher, Skinner, (1982) The Chemistry of the MetalCarbon Bond, , F.R. Hartley, S. Patai, John Wiley, New York, chapter 2Skinner, (1979) Experimental Chemical Thermodynamics, 1. , S. Sunner, M. Mansson, Combustion Calorimetry, Pergamon, Oxford, chapter 11Carson, Spencer, (1984) J. Chem. Thermodyn., 16, p. 423Cox, Pilcher, (1969) Thermochemistry of Organic and Organometallic Compounds, , Academic Press, London and New Yor