Potassium permanganate supported onto alumina in hexane-water is a good oxidizing agent to convert α-hydroxysilanes into acylsilanes. This mild oxidation afforded aroylsilanes having electron-donating groups attached to the aromatic ring, in 70-86% yield.311624572461Saleur, D., Bouillon, J.-P., Portella, C., (1999) Tetrahedron Lett., 40, p. 321Saleur, D., Bouillon, J.-P., Portella, C., (2000) Tetrahedron Lett., 41, p. 1885Tsai, Y.M., Cherng, C.D., Nieh, H.C., Sieh, J.A., (1999) Tetrahedron, 55, p. 14587Takeda, K., Ohtani, Y., (1999) Org. Lett., 1, p. 677Chuang, T.-H., Fang, J.-M., Jiaang, W.-T., Tsai, Y.-M., (1996) J. Org. Chem., 61, p. 1794Chang, S.Y., Jiaang, W.T., Cherng, C.D., Tang, K.H., Huang, C.H., Tsai, Y.M., (1997) J. Org. Chem., 6...
Disclosed is a mild, scalable, and chemoselective catalytic cross-dehydrogenative C–H bond functiona...
Me2SiH2, MeSiH3, and SiH4 are gaseous and flammable silanes that are inconvenient to use in chemical...
The objective of this research is to discover an effective, safe, and low-cost catalyst for ketone h...
Potassium permanganate supported onto alumina in hexane-water is a good oxidizing agent to convert a...
Aromatic acylsilanes [Ar-CO-SiMe3; Ar = C6H5,4-ClC6H4, 2-, 3- and 4-OMeC6H4, 3,4-(OMe)2C6H3 and 3,4-...
An efficient route to hydroxylated aromatics has been developed, via the oxidation of aryl organosil...
In this thesis, we study arylsilane oxidation from both a synthetic and a mechanistic perspective. ...
In recent years, industrial and academic researches have experienced unprecedented changes related t...
The oxidative method for the hydrolysis of 1,3-dithianes was applied to 2-silyl-1,3-dithianes using ...
Disiloxanes possessing a silicon–oxygen linkage are important as frameworks for functional materials...
The goal of this research was to explore the use of aryl silatranes as a replacement for aryl siloxa...
A series of chromium, molybdenum and tungsten incorporated silica extracted from rice husk were prep...
The polar organic molecule propane-1,3-diamine reacted: (i) with a 3-glycidoxypropyltrimethoxysilane...
The aims of this work were two-fold - to enhance the 'latent functionality' of a silicon centre by e...
International audienceα-Alkynyl-α′-trimethylsilylhydrazones are readily oxidized into diazo compound...
Disclosed is a mild, scalable, and chemoselective catalytic cross-dehydrogenative C–H bond functiona...
Me2SiH2, MeSiH3, and SiH4 are gaseous and flammable silanes that are inconvenient to use in chemical...
The objective of this research is to discover an effective, safe, and low-cost catalyst for ketone h...
Potassium permanganate supported onto alumina in hexane-water is a good oxidizing agent to convert a...
Aromatic acylsilanes [Ar-CO-SiMe3; Ar = C6H5,4-ClC6H4, 2-, 3- and 4-OMeC6H4, 3,4-(OMe)2C6H3 and 3,4-...
An efficient route to hydroxylated aromatics has been developed, via the oxidation of aryl organosil...
In this thesis, we study arylsilane oxidation from both a synthetic and a mechanistic perspective. ...
In recent years, industrial and academic researches have experienced unprecedented changes related t...
The oxidative method for the hydrolysis of 1,3-dithianes was applied to 2-silyl-1,3-dithianes using ...
Disiloxanes possessing a silicon–oxygen linkage are important as frameworks for functional materials...
The goal of this research was to explore the use of aryl silatranes as a replacement for aryl siloxa...
A series of chromium, molybdenum and tungsten incorporated silica extracted from rice husk were prep...
The polar organic molecule propane-1,3-diamine reacted: (i) with a 3-glycidoxypropyltrimethoxysilane...
The aims of this work were two-fold - to enhance the 'latent functionality' of a silicon centre by e...
International audienceα-Alkynyl-α′-trimethylsilylhydrazones are readily oxidized into diazo compound...
Disclosed is a mild, scalable, and chemoselective catalytic cross-dehydrogenative C–H bond functiona...
Me2SiH2, MeSiH3, and SiH4 are gaseous and flammable silanes that are inconvenient to use in chemical...
The objective of this research is to discover an effective, safe, and low-cost catalyst for ketone h...