Palladium(0)-catalyzed arylative dearomatization of phenols.

Rousseaux, S
García-Fortanet, J
Del Aguila Sanchez, MA
Buchwald, S

Publication date

January 2011

Abstract

The palladium-catalyzed arylative dearomatization of phenols to yield spirocyclohexadienone products in good to excellent yields has been developed. Preliminary results demonstrate that the formation of the spirocyclic all-carbon quaternary center can be accomplished with high levels of enantiocontrol (up to 91% ee)

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Palladium(0)-catalyzed arylative dearomatization of phenols.

Abstract

Extracted data

Palladium(0)-catalyzed arylative dearomatization of phenols.

Abstract

Extracted data

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