The problem of how to represent networks, and from this representation, derive succinct characterizations of network structure and in particular how this structure evolves with time, is of central importance in complex network analysis. This paper tackles the problem by proposing a thermodynamic framework to represent the structure of time-varying complex networks. More importantly, such a framework provides a powerful tool for better understanding the network time evolution. Specifically, the method uses a recently-developed approximation of the network von Neumann entropy and interprets it as the thermodynamic entropy for networks. With an appropriately-defined internal energy in hand, the temperature between networks at consecutiv...