International audienceIn solvent extraction, the self-assembly of amphiphilic molecules into an organized structure is the phenomenon responsible for the transfer of the metal ion from the aqueous phase to the organic solvent. Despite their significance for chemical engineering and separation science, the forces driving the solute transfer are not fully understood. Instead of assuming the simple complexation reaction with predefined stoichiometry, we model synergistic extraction systems by a colloidal approach that explicitly takes into account the self-assembly resulting from the amphiphilic nature of the extractants. Contrary to the current paradigm of simple stoichiometry behind liquid–liquid extraction, there is a severe polydispersity ...
International audienceThe phase transfer of ions is driven by gradients of chemical potentials rathe...
International audienceIn this article Part II, we consider the application of ienaic modeling for so...
International audienceEfficient formulations used in hydrometallurgy are often based on synergistic ...
International audienceIn solvent extraction, the self-assembly of amphiphilic molecules into an orga...
International audienceIn the second part of this study, we analyze the free energy of transfer in th...
International audienceRecent experimental studies demonstrate the need to take into account weak int...
Among the proposed mechanisms to predict and understand synergism in solvent extraction, the possibi...
International audienceRevisiting aggregation of extractant molecules into water-poor mixed reverse m...
International audienceAmong the proposed mechanisms to predict and understand synergism in solvent e...
In liquid–liquid extraction, synergism emerges when for a defined formulation of the solvent phase, ...
International audienceThe phase transfer of ions is driven by gradients of chemical potentials rathe...
International audienceIn this article Part II, we consider the application of ienaic modeling for so...
International audienceEfficient formulations used in hydrometallurgy are often based on synergistic ...
International audienceIn solvent extraction, the self-assembly of amphiphilic molecules into an orga...
International audienceIn the second part of this study, we analyze the free energy of transfer in th...
International audienceRecent experimental studies demonstrate the need to take into account weak int...
Among the proposed mechanisms to predict and understand synergism in solvent extraction, the possibi...
International audienceRevisiting aggregation of extractant molecules into water-poor mixed reverse m...
International audienceAmong the proposed mechanisms to predict and understand synergism in solvent e...
In liquid–liquid extraction, synergism emerges when for a defined formulation of the solvent phase, ...
International audienceThe phase transfer of ions is driven by gradients of chemical potentials rathe...
International audienceIn this article Part II, we consider the application of ienaic modeling for so...
International audienceEfficient formulations used in hydrometallurgy are often based on synergistic ...