Linear response deviations during recording of diffraction gratings in photopolymers

In a holographic recording is advisable that the diffraction efficiency increases linearly with the exposure in a wide zone of the curve of diffraction efficiency versus energetic exposure and the slope of the curve must be approximately constant before saturation in order to improve the energetic sensitivity and to get reproducibility in different recordings with the same kind of photopolymer, although to find examples of deviations to this behavior it is usual. The more important deviation experimentally observed in photopolymers with high thickness happen when the first maximum in the curve is lower than the second one. This effect is opposed to an overmodulation. We present a main hypothesis related to the dye concentration into the layer and with the molecular weight of the polymer chains generated in the polymerization process in order to explain this effect.This work was supported by “Ministerio de Ciencia e Innovación” (FIS2008-05856-C02-01, FIS2008-05856-C02-02) and “Generalitat Valenciana”, Spain (GVPRE/2008/274)