By analyzing the experimental data for various glass-forming liquids and polymers, we find that the nonexponentiality, β, and the relaxation time, τ, are commonly related: log(τ) is an approximately linear function of 1/β, followed in most cases by a crossover to a higher linear slope. We rationalize this relationship in the recently developed elastic approach to the glass transition. The key to the observed common relationship between β and τ is that the two quantities are governed by the same parameter, the liquid elasticity length, del. The increase of del on lowering temperature increases τ and decreases β, resulting in the observed common relationship between β and τ. In this picture, we also discuss the crossovers of β and τ at low t...
The temperature dependence of the α-relaxation time out of equilibrium has been investigated by mean...
Recently, Nielsen et al. [J. Chem. Phys. 130, 154508 (2009); Philos. Mag. 88, 4101 (2008)] demonstra...
In the present work a comparison among the different functions commonly used to describe the α-relax...
By analyzing the experimental data for various glass-forming liquids and polymers, we find that the ...
Upon decreasing temperature or increasing pressure, a noncrystallizing liquid will vitrify; that is,...
Upon decreasing temperature or increasing pressure, a noncrystallizing liquid will vitrify; that is,...
A major mystery of glass-forming liquids is the non-Arrhenius temperature-dependence of the average ...
We propose that the onset of a glass transition can be defined as the point at which a supercooled l...
We propose that the onset of a glass transition can be defined as the point at which a supercooled l...
A short review on relaxation theories of glass transition is presented. The main attention is paid t...
By now it is well established that the structural α-relaxation time, τ α, of non-associated small mo...
By now it is well established that the structural α-relaxation time, τ α, of non-associated small mo...
Glass forming liquids exhibit upon cooling a striking divergence in the magnitude of the characteris...
We discuss two main universal dynamic crossovers in a liquid that correspond to relaxation times of ...
Abstract. We first review the phenomenology of viscous liquids and the standard models used for expl...
The temperature dependence of the α-relaxation time out of equilibrium has been investigated by mean...
Recently, Nielsen et al. [J. Chem. Phys. 130, 154508 (2009); Philos. Mag. 88, 4101 (2008)] demonstra...
In the present work a comparison among the different functions commonly used to describe the α-relax...
By analyzing the experimental data for various glass-forming liquids and polymers, we find that the ...
Upon decreasing temperature or increasing pressure, a noncrystallizing liquid will vitrify; that is,...
Upon decreasing temperature or increasing pressure, a noncrystallizing liquid will vitrify; that is,...
A major mystery of glass-forming liquids is the non-Arrhenius temperature-dependence of the average ...
We propose that the onset of a glass transition can be defined as the point at which a supercooled l...
We propose that the onset of a glass transition can be defined as the point at which a supercooled l...
A short review on relaxation theories of glass transition is presented. The main attention is paid t...
By now it is well established that the structural α-relaxation time, τ α, of non-associated small mo...
By now it is well established that the structural α-relaxation time, τ α, of non-associated small mo...
Glass forming liquids exhibit upon cooling a striking divergence in the magnitude of the characteris...
We discuss two main universal dynamic crossovers in a liquid that correspond to relaxation times of ...
Abstract. We first review the phenomenology of viscous liquids and the standard models used for expl...
The temperature dependence of the α-relaxation time out of equilibrium has been investigated by mean...
Recently, Nielsen et al. [J. Chem. Phys. 130, 154508 (2009); Philos. Mag. 88, 4101 (2008)] demonstra...
In the present work a comparison among the different functions commonly used to describe the α-relax...