Electrocrystallization and Solubility of Mercury in Alkaline Solution

The chemical thermodynamics of mercury in aqueous sodium hydroxide solution has been investigated through electrochemical polarisation and solubility experiments. A review of thermodynamic data allowed determination of the Hg/HgO electrode potential. Cyclic voltammetry revealed a complex anodic reaction beginning with aqueous dissolution of elemental mercury and subsequent electrocrystallization of mercuric oxide. Cathodic sweeps showed dual reduction reactions, attributed to the presence of aqueous mercury and mercuric oxide. The solubility and hence activity of elemental mercury in sodium hydroxide solution was determined, otherwise known as the Sechenov salt effect. Sodium hydroxide salted mercury out of solution.The accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author