The Lautens group has recently developed a variety of novel multi-metal catalyzed synthetic methodologies involving chiral and achiral ligands. These types of systems are attractive in terms of efficiency as no reaction intermediates need to be isolated thus reducing waste, time and cost. In an attempt to expand this field, the focus of this work is on the synthesis of novel hybrid ligands containing a chiral diene and phosphine moiety for the purposes of Rh/Pd dual-metal catalysis. Achievements include the synthesis of a variety of hybrid ligands and progress towards the optimization of a one-pot one-step Rh/Pd dual-metal catalyzed reaction with these types of ligands. Specifically, this reaction involves the Rh-catalyzed asymmetric co...
Effective and modular synthetic approaches toward phosphine-phosphite ligands and phosphine-phosphon...
textTransition metal-catalyzed carbon-carbon bond-forming reactions are attractive methodological ...
This thesis describes the asymmetric synthesis of functionalized chiral diphosphines via enantiomeri...
The Lautens group has recently developed a variety of novel multi-metal catalyzed synthetic methodol...
Catalytic asymmetric synthesis of a chiral diene ligand with a C2-symmetric norbornadiene as scaffol...
Catalytic asymmetric synthesis of a chiral diene ligand with a C2-symmetric norbornadiene as scaffol...
Chiral dienes are important ligands in asymmetric catalysis but they are less accessible than other ...
International audienceIn 1998, Hayashi and Miyaura reported the first asymmetric conjugate addition ...
Chiral dienes are important ligands in asymmetric catalysis but they are less accessible than other ...
International audienceIn 1998, Hayashi and Miyaura reported the first asymmetric conjugate addition ...
A series of chiral beta-aminophosphine ligands bearing different carbon backbones and electronically...
This thesis summarizes the author’s graduate research on phosphorus ligands synthesis and catalytic ...
This thesis describes the development of rhodium-catalyzed asymmetric ring opening of strained alken...
Effective and modular synthetic approaches toward phosphine-phosphite ligands and phosphine-phosphon...
Effective and modular synthetic approaches toward phosphine-phosphite ligands and phosphine-phosphon...
Effective and modular synthetic approaches toward phosphine-phosphite ligands and phosphine-phosphon...
textTransition metal-catalyzed carbon-carbon bond-forming reactions are attractive methodological ...
This thesis describes the asymmetric synthesis of functionalized chiral diphosphines via enantiomeri...
The Lautens group has recently developed a variety of novel multi-metal catalyzed synthetic methodol...
Catalytic asymmetric synthesis of a chiral diene ligand with a C2-symmetric norbornadiene as scaffol...
Catalytic asymmetric synthesis of a chiral diene ligand with a C2-symmetric norbornadiene as scaffol...
Chiral dienes are important ligands in asymmetric catalysis but they are less accessible than other ...
International audienceIn 1998, Hayashi and Miyaura reported the first asymmetric conjugate addition ...
Chiral dienes are important ligands in asymmetric catalysis but they are less accessible than other ...
International audienceIn 1998, Hayashi and Miyaura reported the first asymmetric conjugate addition ...
A series of chiral beta-aminophosphine ligands bearing different carbon backbones and electronically...
This thesis summarizes the author’s graduate research on phosphorus ligands synthesis and catalytic ...
This thesis describes the development of rhodium-catalyzed asymmetric ring opening of strained alken...
Effective and modular synthetic approaches toward phosphine-phosphite ligands and phosphine-phosphon...
Effective and modular synthetic approaches toward phosphine-phosphite ligands and phosphine-phosphon...
Effective and modular synthetic approaches toward phosphine-phosphite ligands and phosphine-phosphon...
textTransition metal-catalyzed carbon-carbon bond-forming reactions are attractive methodological ...
This thesis describes the asymmetric synthesis of functionalized chiral diphosphines via enantiomeri...