A mini-cavity microwave spectrometer was used to record the rotational spectra arising from 2-phenylethyl methyl ether and its weakly bonded argon complex in the frequency range of 10.5 � 22 GHz. Rotational spectra were found for two stable conformations of the monomer: anti-anti and gauche-anti, which are 1.4 kJ mol$^{-1}$ apart in energy at wB97XD/6-311++G(d,p) level. Doubled rotational transitions, arising from internal motion of the methyl group, were observed for both conformers. The program XIAM was used to fit the rotational constants, centrifugal distortion constants, and barrier to internal rotation to the measured transition frequencies of the A and E internal rotation states. The best global fit values of the rotational constants...
International audienceThe microwave spectrum of o‐methyl anisole (2‐methoxytoluene), CH3OC6H4CH3, ha...
International audienceThe microwave spectrum of o‐methyl anisole (2‐methoxytoluene), CH3OC6H4CH3, ha...
International audienceThe Fourier transform microwave spectrum of p-methyl anisole, CH3C6H4OCH3, was...
A mini-cavity microwave spectrometer was used to record the rotational spectra arising from 2-phenyl...
Author Institution: Department of Chemistry, Wesleyan University, Hall-Atwater Laboratories, 52 Lawn...
Rotational spectra of $alpha$-Methylstyrene, cis-$beta$-Methylstyrene, and trans-$beta$-Methylstyren...
Author Institution: Department of Chemistry, Wesleyan University, Middletown, CT 06459Rotational spe...
Author Institution: Department of Chemistry, University of Virginia, McCormick Rd., P.O. Box 400319,...
Rotational spectra of $alpha$-Methylstyrene, cis-$beta$-Methylstyrene, and trans-$beta$-Methylstyren...
A pulsed molecular beam Fourier transform microwave spectrometer operating in the frequency range 2 ...
We have observed rotational transitions of ethylmethyl ether (CH3CH2OCH3) in the 24-110 GHz frequenc...
International audienceTo determine the structural properties of 2,3-dimethylanisole, a multidiscipli...
International audienceTo determine the structural properties of 2,3-dimethylanisole, a multidiscipli...
International audienceThe microwave spectrum of 2-acetyl-4-methylthiophene (2A4MT) was recorded in t...
International audienceThe microwave spectrum of 2-acetyl-4-methylthiophene (2A4MT) was recorded in t...
International audienceThe microwave spectrum of o‐methyl anisole (2‐methoxytoluene), CH3OC6H4CH3, ha...
International audienceThe microwave spectrum of o‐methyl anisole (2‐methoxytoluene), CH3OC6H4CH3, ha...
International audienceThe Fourier transform microwave spectrum of p-methyl anisole, CH3C6H4OCH3, was...
A mini-cavity microwave spectrometer was used to record the rotational spectra arising from 2-phenyl...
Author Institution: Department of Chemistry, Wesleyan University, Hall-Atwater Laboratories, 52 Lawn...
Rotational spectra of $alpha$-Methylstyrene, cis-$beta$-Methylstyrene, and trans-$beta$-Methylstyren...
Author Institution: Department of Chemistry, Wesleyan University, Middletown, CT 06459Rotational spe...
Author Institution: Department of Chemistry, University of Virginia, McCormick Rd., P.O. Box 400319,...
Rotational spectra of $alpha$-Methylstyrene, cis-$beta$-Methylstyrene, and trans-$beta$-Methylstyren...
A pulsed molecular beam Fourier transform microwave spectrometer operating in the frequency range 2 ...
We have observed rotational transitions of ethylmethyl ether (CH3CH2OCH3) in the 24-110 GHz frequenc...
International audienceTo determine the structural properties of 2,3-dimethylanisole, a multidiscipli...
International audienceTo determine the structural properties of 2,3-dimethylanisole, a multidiscipli...
International audienceThe microwave spectrum of 2-acetyl-4-methylthiophene (2A4MT) was recorded in t...
International audienceThe microwave spectrum of 2-acetyl-4-methylthiophene (2A4MT) was recorded in t...
International audienceThe microwave spectrum of o‐methyl anisole (2‐methoxytoluene), CH3OC6H4CH3, ha...
International audienceThe microwave spectrum of o‐methyl anisole (2‐methoxytoluene), CH3OC6H4CH3, ha...
International audienceThe Fourier transform microwave spectrum of p-methyl anisole, CH3C6H4OCH3, was...