220 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997.Part I. Layered dendrimers were rapidly synthesized using an orthogonal coupling strategy. Fourth generation dendron 71 was prepared in four steps by sequential use of two AB$\sb2$ building blocks 66 and 67 under Mitsunobu esterification and Sonogashira coupling conditions. Further accelerated growth was achieved by merging the orthogonal coupling strategy with Frechet's branched-monomer approach. Thus, sixth generation dendron 81, with molecular formula $\rm C\sb{1292}H\sb{1369}IO\sb{242}$ and a molecular weight of 20897 amu, was synthesized in just three steps from the corresponding AB$\sb4$ monomers 72 and 73. In comparison to the most efficient dendrimer synthesis av...
Synthetic methodologies to develop and program complex self-assembling soft matter have pushed the f...
Self-assemblies with well-defined shapes obtained from combinations of building blocks within comple...
In the context of constructing nonclassical mechanically interlocked dendrimers by employing a conve...
220 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997.Part I. Layered dendrimers we...
Nature consistently relies on large molecules such as proteins to perform many important chemical fu...
Development of complex supramolecular and macromolecular systems is driven by the development of new...
Stiff dendritic macromolecules based on phenylacetylene units have been studied. Methodologies for d...
The directionality and strength of hydrogen bonds has made the synthesis of self-assembling arrays d...
Dendrimers are a unique class of macromolecules that present perfect branching on a molecular scale....
140 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1998.Part II. In Part II, the desi...
ABSTRACT: By taking advantage of the orthogonal nature of thiol-ene coupling and anhydride based est...
Simply mixing a core (black) with defined amounts of branching units (red) and end caps (blue) leads...
128 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2003.In part II, the ability of th...
Dendrons are excellent multifunctional platforms for many different applications. In particular, the...
Self-assembling dendrons that self-organize into liquid crystalline supramolecular dendrimers enable...
Synthetic methodologies to develop and program complex self-assembling soft matter have pushed the f...
Self-assemblies with well-defined shapes obtained from combinations of building blocks within comple...
In the context of constructing nonclassical mechanically interlocked dendrimers by employing a conve...
220 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1997.Part I. Layered dendrimers we...
Nature consistently relies on large molecules such as proteins to perform many important chemical fu...
Development of complex supramolecular and macromolecular systems is driven by the development of new...
Stiff dendritic macromolecules based on phenylacetylene units have been studied. Methodologies for d...
The directionality and strength of hydrogen bonds has made the synthesis of self-assembling arrays d...
Dendrimers are a unique class of macromolecules that present perfect branching on a molecular scale....
140 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 1998.Part II. In Part II, the desi...
ABSTRACT: By taking advantage of the orthogonal nature of thiol-ene coupling and anhydride based est...
Simply mixing a core (black) with defined amounts of branching units (red) and end caps (blue) leads...
128 p.Thesis (Ph.D.)--University of Illinois at Urbana-Champaign, 2003.In part II, the ability of th...
Dendrons are excellent multifunctional platforms for many different applications. In particular, the...
Self-assembling dendrons that self-organize into liquid crystalline supramolecular dendrimers enable...
Synthetic methodologies to develop and program complex self-assembling soft matter have pushed the f...
Self-assemblies with well-defined shapes obtained from combinations of building blocks within comple...
In the context of constructing nonclassical mechanically interlocked dendrimers by employing a conve...