An unprecedented transfer of a thiocyanate (−SCN) group from aroyl/acyl isothiocyanate to alkyl or benzylic bromide is observed in the presence of a tertiary amine. This process is most effective when the bromomethyl proton is less acidic, while the presence of a more acidic proton gives 1,3-oxathiol-2-ylidine and other related products
The new motif – α,α-difluoromethyl thioamide – has been assembled starting from isothiocyanate (as t...
Anhydrous FeCl<SUB>3</SUB> oxidizes potassium thiocyanate to the corresponding radical and promotes ...
A mild, efficient, and practical method for one-step synthesis of alkanoyl and aroyl isothiocyanates...
A regioselective and concomitant transfer of thiocyanate (−SCN) and aroyl/acyl (−COR) groups from ar...
A regioselective and concomitant transfer of thiocyanate (−SCN) and aroyl/acyl (−COR) groups from ar...
N-Bromosulphonamides, synthesized via direct bromination of sulphonamides, react with several types ...
The addition of carbon (Grignard and organolithium reagents) and hydride nucleophiles (Schwartz reag...
A general and facile one-pot protocol for the preparation of a broad range of alkyl and aryl isothio...
In a one-pot strategy we have achieved an efficient method for the synthesis of organic cyanamides s...
For the first time, the crystal structure of a ditribromide reagent 1,1′-(ethane-1,2-diyl)dipyridini...
International audienceThe synthesis of bench-stable electrophilic thiocyanating reagents was depicte...
The cyanation of organic compounds is an important and useful process as it directly provides nitril...
Indoles, pyrroles, oxindoles and aromatic amino compounds undergo smooth thiocyanation with ammonium...
970-972Thioeyanogen reacts in aprotic solvents with allyl and but-3- enyl cobaloximes to give mode...
Two types of rearrangements have been investigated computationally at the B3LYP/6-311+G(d,p) level. ...
The new motif – α,α-difluoromethyl thioamide – has been assembled starting from isothiocyanate (as t...
Anhydrous FeCl<SUB>3</SUB> oxidizes potassium thiocyanate to the corresponding radical and promotes ...
A mild, efficient, and practical method for one-step synthesis of alkanoyl and aroyl isothiocyanates...
A regioselective and concomitant transfer of thiocyanate (−SCN) and aroyl/acyl (−COR) groups from ar...
A regioselective and concomitant transfer of thiocyanate (−SCN) and aroyl/acyl (−COR) groups from ar...
N-Bromosulphonamides, synthesized via direct bromination of sulphonamides, react with several types ...
The addition of carbon (Grignard and organolithium reagents) and hydride nucleophiles (Schwartz reag...
A general and facile one-pot protocol for the preparation of a broad range of alkyl and aryl isothio...
In a one-pot strategy we have achieved an efficient method for the synthesis of organic cyanamides s...
For the first time, the crystal structure of a ditribromide reagent 1,1′-(ethane-1,2-diyl)dipyridini...
International audienceThe synthesis of bench-stable electrophilic thiocyanating reagents was depicte...
The cyanation of organic compounds is an important and useful process as it directly provides nitril...
Indoles, pyrroles, oxindoles and aromatic amino compounds undergo smooth thiocyanation with ammonium...
970-972Thioeyanogen reacts in aprotic solvents with allyl and but-3- enyl cobaloximes to give mode...
Two types of rearrangements have been investigated computationally at the B3LYP/6-311+G(d,p) level. ...
The new motif – α,α-difluoromethyl thioamide – has been assembled starting from isothiocyanate (as t...
Anhydrous FeCl<SUB>3</SUB> oxidizes potassium thiocyanate to the corresponding radical and promotes ...
A mild, efficient, and practical method for one-step synthesis of alkanoyl and aroyl isothiocyanates...
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