The influence of chiral auxiliaries is enhanced within zeolites
- Jayaraman, Sivaguru
- Uppili, Sundararajan
- Natarajan, Arunkumar
- Joy, Abraham
- Chong, Kenneth C. W.
- Netherton, Matthew R.
- Zenova, Alla
- Scheffer, J. R.
- Ramamurthy, V.
DOIAbstract
Zeolites significantly enhance the influence of chiral auxiliaries during photochemical reactions. The generality of this phenomenon has been tested with three independent examples. Chiral auxiliaries that lead to 1:1 mixtures of diastereomers in solution give products in up to 80% diastereomeric excess in the presence of faujasite type zeolites
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