Total synthesis of (+)-aculeatin D and (+)-6-epi-aculeatin D

Yadav, J. S.
Raghavendra Rao, K. V.
Ravindar, K.
Subba Reddy, B. V.

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Publication date

January 2010

DOI

10.1055/s-0029-1218546

Publisher

Thieme Medical Publishers

Abstract

The stereoselective total synthesis of spiroketal natural product (+)-aculeatin D and unnatural (+)-6-epi-aculeatin D has been accomplished. Sharpless kinetic resolution of secondary allylic alcohol and phenyliodine(III) bis(trifluoroacetate) (PIFA)-mediated oxidative spirocyclization were used as key steps in this synthesis

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Total synthesis of (+)-aculeatin D and (+)-6-epi-aculeatin D

Abstract

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Total synthesis of (+)-aculeatin D and (+)-6-epi-aculeatin D

Abstract

Extracted data

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