The total synthesis of the diarylheptanoids (-)-diospongin A (1) and B (2) was achieved stereoselectively via the δ-lactone intermediate 6. The key reactions involved are a stereoselective reduction of β-keto ester and the Horner-Wadsworth-Emmons and intramolecular oxy-Michael reactions
6-Substituted-2H-dihydropyran-4-one products of the Maitland–Japp reaction have been converted into ...
Proposed is at total synthesis of the steroid desogestrel, utilizing a 1,4-addition/alkylation react...
A highly stereoselective formal total synthesis of homogynolide-B via the ketoketals 4 and the ketos...
6-Substituted-2H-dihydropyran-4-one products of the Maitland-Japp reaction have been converted into ...
The first total synthesis of (−)-diospongin B has been achieved starting from benzaldehyde using chi...
We describe here a divergent total synthesis of all of the four stereoisomers of dihydrokawain-5-ol ...
A concise and efficient total synthesis of diospongin A is described; it utilizes Prins cyclization ...
Oxygen-containing heterocycles such as pyrans are a common substructure present in a variety of natu...
A short and flexible [3+2+1] synthetic strategy was developed for the synthesis of substituted tetra...
The total synthesis of lactone 1 has been described. The convergent asymmetric synthesis relies on t...
An efficient, 6-step synthesis of the (-)-diketone (122) from (+)-carvomenthone (123) is described....
Stereoselective 9-step conversions of the ketone 17 into the tricyclic ketone 31 via two similar syn...
This work outlines two different projects. The first project was the study of a stereodivergent oxy-...
Total syntheses of styryl lactones, leiocarpin C and (+)-goniodiol have been accomplished in a highl...
A stereoselective synthesis of the pentaketide lactone (3R,4S,5S,9S)-3,5,9-trihydroxy-4-methylundeca...
6-Substituted-2H-dihydropyran-4-one products of the Maitland–Japp reaction have been converted into ...
Proposed is at total synthesis of the steroid desogestrel, utilizing a 1,4-addition/alkylation react...
A highly stereoselective formal total synthesis of homogynolide-B via the ketoketals 4 and the ketos...
6-Substituted-2H-dihydropyran-4-one products of the Maitland-Japp reaction have been converted into ...
The first total synthesis of (−)-diospongin B has been achieved starting from benzaldehyde using chi...
We describe here a divergent total synthesis of all of the four stereoisomers of dihydrokawain-5-ol ...
A concise and efficient total synthesis of diospongin A is described; it utilizes Prins cyclization ...
Oxygen-containing heterocycles such as pyrans are a common substructure present in a variety of natu...
A short and flexible [3+2+1] synthetic strategy was developed for the synthesis of substituted tetra...
The total synthesis of lactone 1 has been described. The convergent asymmetric synthesis relies on t...
An efficient, 6-step synthesis of the (-)-diketone (122) from (+)-carvomenthone (123) is described....
Stereoselective 9-step conversions of the ketone 17 into the tricyclic ketone 31 via two similar syn...
This work outlines two different projects. The first project was the study of a stereodivergent oxy-...
Total syntheses of styryl lactones, leiocarpin C and (+)-goniodiol have been accomplished in a highl...
A stereoselective synthesis of the pentaketide lactone (3R,4S,5S,9S)-3,5,9-trihydroxy-4-methylundeca...
6-Substituted-2H-dihydropyran-4-one products of the Maitland–Japp reaction have been converted into ...
Proposed is at total synthesis of the steroid desogestrel, utilizing a 1,4-addition/alkylation react...
A highly stereoselective formal total synthesis of homogynolide-B via the ketoketals 4 and the ketos...
DOI
Add to ORKG