Acid catalysed rearrangement of the endo̲-alcohol (9) leads to the ketones (11) and (12) having the bicyclo(3.2.1) and bicyclo(2.2.2) moieties. An efficient entry into spiro(4.5)decane and eremane system, as exemplified by the total synthesis of (±)-hinesol (2) and its 10-epimer (3) is reported
Synthesis of 8-bromo-1-hydroxytricyclo[5.3.1.0(2,6)]undecadienones 7 and 8 from endo annulated bicyc...
The stereochemistry of reaction of phenylmagnesium bromide with camphor (43) has been determined. Th...
A general and stereoselective methodology for the synthesis of bridged bicyclic octenones having var...
Acid catalysed rearrangement of the endo-alcohol (9) leads to the ketones (11) and (12) having the b...
An efficient strategy for the construction of the spiro[4,5]decane and eremane systems is described ...
The work described in this thesis involves two separate applications of the thermal rearrangement of...
Synthesis of 1-hydroxy[5.3.1.0(2,6)]undecadienones 15-18 from annulated bicyclo[2.2.2]octenones 10-1...
A methodology for the synthesis of novel spiro-cyclohexene bicyclo [2.2.2] octane derivatives, inclu...
A novel, general and stereoselective route to spiroannulated bicyclo[2.2.2]octenones and their trans...
A novel one step regio- and stereoselective synthesis of functionalised bicyclo[2.2.2]octenones from...
In Chapter 1, rearrangements of 4-substituted bicyclo[2.2.2]oct-2-enyl-5-selenophenyl esters are exp...
A formal total synthesis of (±)-homogynolide-B, a sesquiterpene containing an α-spiro-β-methylene-γ-...
The thermal rearrangements of the bicyclo[2.1.0]pentane-5,2′-methylenecyclopropanes fall into two cl...
Mediated by AlCl(3), substituted spiro[4.5]deca-tetraenes underwent novel and selective skeletal rea...
The enantioselective α-deprotonation-rearrangement of bicycloalkene-derived epoxides (4,9 and 13) to...
Synthesis of 8-bromo-1-hydroxytricyclo[5.3.1.0(2,6)]undecadienones 7 and 8 from endo annulated bicyc...
The stereochemistry of reaction of phenylmagnesium bromide with camphor (43) has been determined. Th...
A general and stereoselective methodology for the synthesis of bridged bicyclic octenones having var...
Acid catalysed rearrangement of the endo-alcohol (9) leads to the ketones (11) and (12) having the b...
An efficient strategy for the construction of the spiro[4,5]decane and eremane systems is described ...
The work described in this thesis involves two separate applications of the thermal rearrangement of...
Synthesis of 1-hydroxy[5.3.1.0(2,6)]undecadienones 15-18 from annulated bicyclo[2.2.2]octenones 10-1...
A methodology for the synthesis of novel spiro-cyclohexene bicyclo [2.2.2] octane derivatives, inclu...
A novel, general and stereoselective route to spiroannulated bicyclo[2.2.2]octenones and their trans...
A novel one step regio- and stereoselective synthesis of functionalised bicyclo[2.2.2]octenones from...
In Chapter 1, rearrangements of 4-substituted bicyclo[2.2.2]oct-2-enyl-5-selenophenyl esters are exp...
A formal total synthesis of (±)-homogynolide-B, a sesquiterpene containing an α-spiro-β-methylene-γ-...
The thermal rearrangements of the bicyclo[2.1.0]pentane-5,2′-methylenecyclopropanes fall into two cl...
Mediated by AlCl(3), substituted spiro[4.5]deca-tetraenes underwent novel and selective skeletal rea...
The enantioselective α-deprotonation-rearrangement of bicycloalkene-derived epoxides (4,9 and 13) to...
Synthesis of 8-bromo-1-hydroxytricyclo[5.3.1.0(2,6)]undecadienones 7 and 8 from endo annulated bicyc...
The stereochemistry of reaction of phenylmagnesium bromide with camphor (43) has been determined. Th...
A general and stereoselective methodology for the synthesis of bridged bicyclic octenones having var...
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