A formal total synthesis of the marine sesquiterpene (±)-9-isocyanoneopupukeanane starting from the readily available monoterpene carvone has been accomplished employing a combination of intermolecular Michael addition-intramolecular Michael addition reaction and an intramolecular rhodium carbenoid C-H insertion reaction as key steps, and identifying the isopropenyl group as a masked hydroxy group
Carvone is a sustainable and readily available starting material for organic synthesis. Herein, we p...
Enantiospecific synthesis of the natural enantiomer of the marine sesquiterpene (-)-4-thiocyanatoneo...
Based on hydrogenolysis of suitably substituted ,\(\beta\)-allylic carbinols with sodium and alcohol...
A formal total synthesis of the marine sesquiterpene $(\pm)$-9-isocyanoneopupukeanane, starting from...
Enantiospecific synthesis of both enantiomers of the marine sesquiterpene 2-thiocyanatoneopupukeanan...
The first enantiospecific total synthesis of (−)-9-pupukeanone, starting from (R)-carvone employing ...
The first synthesis of a chiral neopupukeanane starting, from (R)-carvone and employing a double Mic...
The first synthesis of a chiral neopupukeanane starting, from (R)-carvone and employing a double Mic...
The first enantiospecific total synthesis of (-)-9-pupukeanone, starting from (R)-carvone employing ...
A stereoselective total synthesis of the tricyclic sesquiterpene (−)-seychellene, starting from (R)-...
An enantiospecific synthesis of (−)-2-pupukeanone, starting from (R)-carvone employing a Michael–Mic...
Enantiospecific synthesis of the natural enantiomer of the marine sesquiterpene (−)-4-thiocyanatoneo...
A synthesis of (±)-9-pupukeanone (7) is described. The key reaction was the establishment of the tri...
Enantiospecific first total synthesis of the angular triquinane sesquiterpene (65,7R)-silphiperfolan...
A formal total synthesis of diisocyanoadociane, a marine diterpenoid with potent antimalarial proper...
Carvone is a sustainable and readily available starting material for organic synthesis. Herein, we p...
Enantiospecific synthesis of the natural enantiomer of the marine sesquiterpene (-)-4-thiocyanatoneo...
Based on hydrogenolysis of suitably substituted ,\(\beta\)-allylic carbinols with sodium and alcohol...
A formal total synthesis of the marine sesquiterpene $(\pm)$-9-isocyanoneopupukeanane, starting from...
Enantiospecific synthesis of both enantiomers of the marine sesquiterpene 2-thiocyanatoneopupukeanan...
The first enantiospecific total synthesis of (−)-9-pupukeanone, starting from (R)-carvone employing ...
The first synthesis of a chiral neopupukeanane starting, from (R)-carvone and employing a double Mic...
The first synthesis of a chiral neopupukeanane starting, from (R)-carvone and employing a double Mic...
The first enantiospecific total synthesis of (-)-9-pupukeanone, starting from (R)-carvone employing ...
A stereoselective total synthesis of the tricyclic sesquiterpene (−)-seychellene, starting from (R)-...
An enantiospecific synthesis of (−)-2-pupukeanone, starting from (R)-carvone employing a Michael–Mic...
Enantiospecific synthesis of the natural enantiomer of the marine sesquiterpene (−)-4-thiocyanatoneo...
A synthesis of (±)-9-pupukeanone (7) is described. The key reaction was the establishment of the tri...
Enantiospecific first total synthesis of the angular triquinane sesquiterpene (65,7R)-silphiperfolan...
A formal total synthesis of diisocyanoadociane, a marine diterpenoid with potent antimalarial proper...
Carvone is a sustainable and readily available starting material for organic synthesis. Herein, we p...
Enantiospecific synthesis of the natural enantiomer of the marine sesquiterpene (-)-4-thiocyanatoneo...
Based on hydrogenolysis of suitably substituted ,\(\beta\)-allylic carbinols with sodium and alcohol...
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