The isolation and crystal structure of a cyclic selenenate ester derived from bis(2,6-diformyl-4-tert-butylphenyl)diselenide and its glutathione peroxidase-like activity

Zade, Sanjio S.
Singh, Harkesh B.
Butcher, Ray J.

Open link

Publication date

August 2004

DOI

10.1002/anie.200460380/abstract

Publisher

John Wiley and Sons

Abstract

Enzyme mimicry: Halogenation of diselenide 1 affords the cyclic selenenate ester 2 (see scheme) through a highly unstable selenenic acid intermediate. Compound 2 exhibits a strong intramolecular nonbonding Se···O interaction. Both 1 and 2 show excellent glutathione peroxidase-like catalytic activity

Extracted data

We use cookies to provide a better user experience.

Data Protection

The isolation and crystal structure of a cyclic selenenate ester derived from bis(2,6-diformyl-4-tert-butylphenyl)diselenide and its glutathione peroxidase-like activity

Abstract

Extracted data

The isolation and crystal structure of a cyclic selenenate ester derived from bis(2,6-diformyl-4-tert-butylphenyl)diselenide and its glutathione peroxidase-like activity

Abstract

Extracted data

Related items

Related items