Dehalogenation of five assorted gem-dibromocyclopropanes with zinc in dimethylformamide is described. Monobromocyclopropanes, allenes are fully saturated cyclopropanes are obtained. The method is of preparative value only in certain cases
[[abstract]]Simple and mild methods for the synthesis of allenes, employing indium- and zinc-mediate...
International audienceThe unique combination of Zn/LiCl allowed generation of reactive zinc enolate ...
The reduction of diphenylcyclopropenone with zinc was investigated under a variety of conditions. Th...
In an attempt to synthesize 1,1-dimethylsilicocyclopropane, the reactions of bis- (chloromethyl)-dim...
[[abstract]]"A series of gem-dibromocyclopropanes were treated with various metal complexes. Among t...
The bromination of cyclopropanes using potassium bromide and cerium(IV) ammonium nitrate (CAN) in a ...
On treatment with Bu4N+ F-, cyclopropanecarboxylates I (R = Cl; R1 = Cl, F; R2 = OCMe3) undergo Cl-F...
gem-Dihalocyclopropanes (1) are an important class of compound that play significant roles in contem...
A two-step process for the synthesis of trifluoromethyl-substituted cyclopropanes is described. Halo...
The cyclopropylamine motif is often found in both natural and pharmaceutical compounds. Our group ha...
Cyclopropanation reactions using zinc carbenoids are a powerful means to access cyclopropanes. Descr...
gem-Dichlorocyclopropanes were effectively reduced by lithium aluminum hydride, and monocylopropanes...
Optically active trans-dipropylcyclopropane (I) and its optically inactive cis isomer (II) were prep...
gem-Dihalocyclopropanes are readily prepared by dihalocarbene addition to the corresponding alkene. ...
Methylenecyclopropene was generated under two different reaction conditions. The passage of 2-chloro...
[[abstract]]Simple and mild methods for the synthesis of allenes, employing indium- and zinc-mediate...
International audienceThe unique combination of Zn/LiCl allowed generation of reactive zinc enolate ...
The reduction of diphenylcyclopropenone with zinc was investigated under a variety of conditions. Th...
In an attempt to synthesize 1,1-dimethylsilicocyclopropane, the reactions of bis- (chloromethyl)-dim...
[[abstract]]"A series of gem-dibromocyclopropanes were treated with various metal complexes. Among t...
The bromination of cyclopropanes using potassium bromide and cerium(IV) ammonium nitrate (CAN) in a ...
On treatment with Bu4N+ F-, cyclopropanecarboxylates I (R = Cl; R1 = Cl, F; R2 = OCMe3) undergo Cl-F...
gem-Dihalocyclopropanes (1) are an important class of compound that play significant roles in contem...
A two-step process for the synthesis of trifluoromethyl-substituted cyclopropanes is described. Halo...
The cyclopropylamine motif is often found in both natural and pharmaceutical compounds. Our group ha...
Cyclopropanation reactions using zinc carbenoids are a powerful means to access cyclopropanes. Descr...
gem-Dichlorocyclopropanes were effectively reduced by lithium aluminum hydride, and monocylopropanes...
Optically active trans-dipropylcyclopropane (I) and its optically inactive cis isomer (II) were prep...
gem-Dihalocyclopropanes are readily prepared by dihalocarbene addition to the corresponding alkene. ...
Methylenecyclopropene was generated under two different reaction conditions. The passage of 2-chloro...
[[abstract]]Simple and mild methods for the synthesis of allenes, employing indium- and zinc-mediate...
International audienceThe unique combination of Zn/LiCl allowed generation of reactive zinc enolate ...
The reduction of diphenylcyclopropenone with zinc was investigated under a variety of conditions. Th...
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