Mean spherical model-structure of liquid argon

A new formulation for S(k), the structure factor, has been obtained, treating the square-well potential as a perturbation on the hard-core in the mean spherical model approximation. The potential parameters have been varied not only to get a satisfactory peak height at the fitted temperature but also over a wide range of temperatures and densities. The agreement between the computed and experimental structure factor values shows that the representation of the attractive tail by a square-well potential yields a satisfactory method in understanding the structure of liquid argon