Detailed average magnetic susceptibility (295-4.2 K) and average magnetisation (20-2 K, 50-10 kOe) are reported for two novel spin-mixed iron(III) porphyrins, namely Fe(TPP)ClO4 and Fe(OEP)ClO4. The results confirm an S = 3/2 ground state substantially spin-mixed with a low-lying S = 5/2 state, but do not agree in detail with the crystal-field model of Maltempo
We have investigated computationally the magnetic spin state of free metalloporphyrins and how magne...
Contrary to expectations based on the spectrochemical series, H2O is found to be a significantly wea...
We report the synthesis, structure, and spectroscopic characterization of 1,2-bis[μ-hydroxo iron(I...
The proton magnetic resonance studies on the perchlorato iron(III) porphyrins in solution have been ...
A mononuclear iron III porphyrin compound exhibiting unexpectedly slow magnetic relaxation, which i...
International audienceA mononuclear iron(III) porphyrin compound exhibiting unexpectedly slow magnet...
Mössbauer spectra of a polycrystalline form of oxidized chloro‐5,10,15,20‐tetra(mesityl)porphyrin‐ a...
The proton NMR spectra of unligated ferrous porphyrins, proposed to exist in the intermediate S = 1 ...
[[abstract]]Several biological model complexes of cytochrome c oxidase analogues, such as X2(TPP)2Fe...
In this work, a number of physical techniques are used to study the behaviour and properties of diff...
A series of magnetic, ionic-substituted tetrapyridyl metalloporphyrins, [tetrakis(N-octyl-4-pyridini...
Five-coordinate iron(III) porphyrin complexes can exist in high-spin (S = 5/2), intermediate-spin (S...
International audienceParamagnetic NMR spectroscopy was used to characterize the influence of small ...
The availability of the parent compound, meso-hexaethylporphodimetheneiron(II), [(Et6N4)Fe] (2), of ...
A quasi-one-dimensional three-legged iron phosphate ladder, containing iron atoms connected through ...
We have investigated computationally the magnetic spin state of free metalloporphyrins and how magne...
Contrary to expectations based on the spectrochemical series, H2O is found to be a significantly wea...
We report the synthesis, structure, and spectroscopic characterization of 1,2-bis[μ-hydroxo iron(I...
The proton magnetic resonance studies on the perchlorato iron(III) porphyrins in solution have been ...
A mononuclear iron III porphyrin compound exhibiting unexpectedly slow magnetic relaxation, which i...
International audienceA mononuclear iron(III) porphyrin compound exhibiting unexpectedly slow magnet...
Mössbauer spectra of a polycrystalline form of oxidized chloro‐5,10,15,20‐tetra(mesityl)porphyrin‐ a...
The proton NMR spectra of unligated ferrous porphyrins, proposed to exist in the intermediate S = 1 ...
[[abstract]]Several biological model complexes of cytochrome c oxidase analogues, such as X2(TPP)2Fe...
In this work, a number of physical techniques are used to study the behaviour and properties of diff...
A series of magnetic, ionic-substituted tetrapyridyl metalloporphyrins, [tetrakis(N-octyl-4-pyridini...
Five-coordinate iron(III) porphyrin complexes can exist in high-spin (S = 5/2), intermediate-spin (S...
International audienceParamagnetic NMR spectroscopy was used to characterize the influence of small ...
The availability of the parent compound, meso-hexaethylporphodimetheneiron(II), [(Et6N4)Fe] (2), of ...
A quasi-one-dimensional three-legged iron phosphate ladder, containing iron atoms connected through ...
We have investigated computationally the magnetic spin state of free metalloporphyrins and how magne...
Contrary to expectations based on the spectrochemical series, H2O is found to be a significantly wea...
We report the synthesis, structure, and spectroscopic characterization of 1,2-bis[μ-hydroxo iron(I...
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