Silyl enol ethers (2) react with tributyl [(phenylthio) chloromethyl] stannane (1) in the presence of Zinc bromide to give β-phenylthiomethylstannyl ketones (3) in good yields. Silyl dienol ethers (4) mainly give products (5) due to γ-attack, under these conditions
Ketones are reported to be conveniently converted into their α-tolylsulfinylated derivatives. This n...
A Ni-catalyzed stannylation of aryl esters with air- and moisture-insensitive silylstannyl reagents ...
Ketones undergo in situ enol silane formation in the presence of trimethylsilyl trifluoromethanesulf...
para-Methoxybenzyl methyl ether acts as an alkylating agent for thiols in the presence of trimethyls...
Tributylstannyl-1,3-dienes could be considered synthetic equivalents of conjugated dienic anions. Th...
[[abstract]]A mixture of Zn, CeCl3, 3-bromo-1-tributylstannylpropene and aldehyde or ketone in THF/P...
Reaction of silyl dithiolanes with electrophiles can be efficiently promoted by catalytic amounts of...
Allyl propionates are readily ionized by trimethylsilyl trifluoromethanesulfonate to provide allyl c...
Silyl enol ethers can be effectively alkylated with primary n-alkyl iodides in the presence of silve...
1-Phenylthio-3-vinyl-cyclohex-1-en-3-ol (2) has been synthesized and investigated as a new bis-annel...
The Lewis acids CH3SiCl3 (0.33 - 1.0 equivalents) and (CH3O)2SiCH3Cl (1.0 equivalent) promote the ad...
The copper (I) catalysed coupling of α-metallated cyclic enol ethers with organolithium of Grignard ...
The substitution of a siloxy group using thiosilanes smoothly occurred in the presence of InI3 catal...
The preparation of the titte compounds is reported starting from the corresponding bromo derivatives...
Durch die Verwendung des Phenyldimethylsilylrestes ist es gelungen, das bis dahin unbekannte Tris(ph...
Ketones are reported to be conveniently converted into their α-tolylsulfinylated derivatives. This n...
A Ni-catalyzed stannylation of aryl esters with air- and moisture-insensitive silylstannyl reagents ...
Ketones undergo in situ enol silane formation in the presence of trimethylsilyl trifluoromethanesulf...
para-Methoxybenzyl methyl ether acts as an alkylating agent for thiols in the presence of trimethyls...
Tributylstannyl-1,3-dienes could be considered synthetic equivalents of conjugated dienic anions. Th...
[[abstract]]A mixture of Zn, CeCl3, 3-bromo-1-tributylstannylpropene and aldehyde or ketone in THF/P...
Reaction of silyl dithiolanes with electrophiles can be efficiently promoted by catalytic amounts of...
Allyl propionates are readily ionized by trimethylsilyl trifluoromethanesulfonate to provide allyl c...
Silyl enol ethers can be effectively alkylated with primary n-alkyl iodides in the presence of silve...
1-Phenylthio-3-vinyl-cyclohex-1-en-3-ol (2) has been synthesized and investigated as a new bis-annel...
The Lewis acids CH3SiCl3 (0.33 - 1.0 equivalents) and (CH3O)2SiCH3Cl (1.0 equivalent) promote the ad...
The copper (I) catalysed coupling of α-metallated cyclic enol ethers with organolithium of Grignard ...
The substitution of a siloxy group using thiosilanes smoothly occurred in the presence of InI3 catal...
The preparation of the titte compounds is reported starting from the corresponding bromo derivatives...
Durch die Verwendung des Phenyldimethylsilylrestes ist es gelungen, das bis dahin unbekannte Tris(ph...
Ketones are reported to be conveniently converted into their α-tolylsulfinylated derivatives. This n...
A Ni-catalyzed stannylation of aryl esters with air- and moisture-insensitive silylstannyl reagents ...
Ketones undergo in situ enol silane formation in the presence of trimethylsilyl trifluoromethanesulf...