Acylketene O,S-acetals 1a-k undergo efficient and selective conjugate displacement of alkylthio group with organocopper(l) reagents to afford the corresponding 6-alkoxy/aryloxy enones 2-21 in good yields
A new synthetic approach to thiolactones that employs an efficient acyl thiol-ene (ATE) or acyl thio...
The acylation of organometallics with carboxylic acid derivatives has been generally adopted as a ch...
This thesis is divided into three parts: conjugate additions of organocopper reagents, DDQ oxidation...
a,ßethylenic ketones and a,ß, a',ß' diethylenic ketones with a stereodefined substitution pattern ar...
The synthesis of acylketene O,S-dialkyl acetals 2a-p and acylketene O-aryl S-alkyl acetals 6a-i is d...
Cross-coupling reactions of alpha-acetoxy carboxylic acid chlorides with organocopper reagents, deri...
A novel route to 2-alkoxy/aryloxy-4-arylthiophenes 4a-k and the corresponding 3,4-annulated thiophen...
1,1-Dimethyl-3-(phenyldio)-propane 4 was deprotonated with t-BuLi, then converted to the correspondi...
Chemoselective cross-coupling reactions of monoesters of dicarboxylic acid chlorides with organocopp...
Isothiourea DHPB promotes the diastereoselective C-acylation of silyl ketene acetals with anhydrides...
Isothiourea DHPB promotes the diastereoselective C-acylation of silyl ketene acetals with anhydrides...
Eater enolates are generated by reductive α-deacetoxylation of α-acetoxy-α-arylmaloni...
The ketoketene-S,S-acetals (5a-c) react with guanidine and thiourea in the presence of alcoholic sod...
The acylketene S,N-acetals 1 react with one equivalent of malonyl chloride in the presence of trieth...
The dynamic kinetic resolution of secondary alcohols using a lipase and a ruthenium catalyst require...
A new synthetic approach to thiolactones that employs an efficient acyl thiol-ene (ATE) or acyl thio...
The acylation of organometallics with carboxylic acid derivatives has been generally adopted as a ch...
This thesis is divided into three parts: conjugate additions of organocopper reagents, DDQ oxidation...
a,ßethylenic ketones and a,ß, a',ß' diethylenic ketones with a stereodefined substitution pattern ar...
The synthesis of acylketene O,S-dialkyl acetals 2a-p and acylketene O-aryl S-alkyl acetals 6a-i is d...
Cross-coupling reactions of alpha-acetoxy carboxylic acid chlorides with organocopper reagents, deri...
A novel route to 2-alkoxy/aryloxy-4-arylthiophenes 4a-k and the corresponding 3,4-annulated thiophen...
1,1-Dimethyl-3-(phenyldio)-propane 4 was deprotonated with t-BuLi, then converted to the correspondi...
Chemoselective cross-coupling reactions of monoesters of dicarboxylic acid chlorides with organocopp...
Isothiourea DHPB promotes the diastereoselective C-acylation of silyl ketene acetals with anhydrides...
Isothiourea DHPB promotes the diastereoselective C-acylation of silyl ketene acetals with anhydrides...
Eater enolates are generated by reductive α-deacetoxylation of α-acetoxy-α-arylmaloni...
The ketoketene-S,S-acetals (5a-c) react with guanidine and thiourea in the presence of alcoholic sod...
The acylketene S,N-acetals 1 react with one equivalent of malonyl chloride in the presence of trieth...
The dynamic kinetic resolution of secondary alcohols using a lipase and a ruthenium catalyst require...
A new synthetic approach to thiolactones that employs an efficient acyl thiol-ene (ATE) or acyl thio...
The acylation of organometallics with carboxylic acid derivatives has been generally adopted as a ch...
This thesis is divided into three parts: conjugate additions of organocopper reagents, DDQ oxidation...