Kinetics of hydroformylation of 1-decene using homogeneous HRh(CO)(PPh<SUB>3</SUB>)<SUB>3</SUB> catalyst: a molecular level approach

Divekar, S. S.
Deshpande, R. M.
Chaudhari, R. V.

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Publication date

January 1993

DOI

10.1007/BF00767385

Publisher

Springer-Verlag

Abstract

The kinetics of hydroformylation of 1-decene using homogenous HRh(CO)(PPh3)3 catalyst has been reported in the temperature range of 50-70 °C. The effect of catalyst,P H 2,P CO, and 1-decene concentration on the rate of hydroformylation has been studied. Based on the analysis of initial rate data, a rate equation has been proposed and kinetic parameters evaluated. The activation energy was found to be 11.76 kcal/mol. A molecular level approach to kinetic modelling has also been illustrated. The rate equation derived assuming oxidative addition of H2 as a rate determining step, has been found to represent the data satisfactorily. The rate parameters for the mechanistic model have been evaluated for the data at 60 °C

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Kinetics of hydroformylation of 1-decene using homogeneous HRh(CO)(PPh<SUB>3</SUB>)<SUB>3</SUB> catalyst: a molecular level approach

Abstract

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Kinetics of hydroformylation of 1-decene using homogeneous HRh(CO)(PPh<SUB>3</SUB>)<SUB>3</SUB> catalyst: a molecular level approach

Abstract

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