Add to ORKGA comprehensive analysis of the influence of the chiral auxiliary on the α-aminoxylation of titanium(IV) enolates with TEMPO indicated that (S) 4-tert-butyl-1-oxazolidine-2-thione is the most appropriate scaffold to provide a single diastereomer in high yields for a variety of substrates, which converts such a radical reaction into a highly chemo- and stereoselective oxidatio
The stereoselective addition of the titanium (IV) enolates derived from (S)-4-isopropyl-N-4-chlorobu...
Ephedrine-based imidazolidin-2-one chiral auxiliaries afford good syn stereoselectivity in the addit...
The highly diastereoselective conjugate addition of lithium N-benzyl-N-α-methylbenzylamide with enoa...
A highly efficient and straightforward aminoxylation of titanium(IV) enolates from (S)-N-acyl-4-benz...
A novel approach to synthesize enantiomerically pure α-hydroxy carboxylic derivatives is reported. A...
The sterochemical outcome of the addition of chiral titanium enolates to gamma-lactols derived from ...
Here, we present a new stereoselective alkylation of titanium(IV) enolates of chiral N-acyl oxazolid...
In the present Thesis we continued a previous study of the nucleophilic character of titanium(IV) en...
[eng] In the present Thesis we continued a previous study of the nucleophilic character of titanium...
[EN]Here, we present a new stereoselective alkylation of titanium(IV) enolates of chiral N-acyl oxaz...
A mild and versatile synthesis of a-oxy-6-amino esters has been performed by condensation of the chl...
[eng] This thesis consists in the development of a new methodology of α-alkylation of carbonyl compo...
Programa de Doctorat en Química OrgànicaThis thesis consists in the development of a new methodology...
Simple treatment of chiral titanium(IV) enolates with diacyl peroxides produces highly diastereosele...
Lewis acid-mediated substrate-controlled reactions of the titanium(IV) enolates of chiral a-benzylox...
The stereoselective addition of the titanium (IV) enolates derived from (S)-4-isopropyl-N-4-chlorobu...
Ephedrine-based imidazolidin-2-one chiral auxiliaries afford good syn stereoselectivity in the addit...
The highly diastereoselective conjugate addition of lithium N-benzyl-N-α-methylbenzylamide with enoa...
A highly efficient and straightforward aminoxylation of titanium(IV) enolates from (S)-N-acyl-4-benz...
A novel approach to synthesize enantiomerically pure α-hydroxy carboxylic derivatives is reported. A...
The sterochemical outcome of the addition of chiral titanium enolates to gamma-lactols derived from ...
Here, we present a new stereoselective alkylation of titanium(IV) enolates of chiral N-acyl oxazolid...
In the present Thesis we continued a previous study of the nucleophilic character of titanium(IV) en...
[eng] In the present Thesis we continued a previous study of the nucleophilic character of titanium...
[EN]Here, we present a new stereoselective alkylation of titanium(IV) enolates of chiral N-acyl oxaz...
A mild and versatile synthesis of a-oxy-6-amino esters has been performed by condensation of the chl...
[eng] This thesis consists in the development of a new methodology of α-alkylation of carbonyl compo...
Programa de Doctorat en Química OrgànicaThis thesis consists in the development of a new methodology...
Simple treatment of chiral titanium(IV) enolates with diacyl peroxides produces highly diastereosele...
Lewis acid-mediated substrate-controlled reactions of the titanium(IV) enolates of chiral a-benzylox...
The stereoselective addition of the titanium (IV) enolates derived from (S)-4-isopropyl-N-4-chlorobu...
Ephedrine-based imidazolidin-2-one chiral auxiliaries afford good syn stereoselectivity in the addit...
The highly diastereoselective conjugate addition of lithium N-benzyl-N-α-methylbenzylamide with enoa...