Add to ORKGChloromethylgold(I) complexes of phosphine, phosphite, and N-heterocyclic carbene ligands are easily synthesized by reaction of trimethylsilyldiazomethane with the corresponding gold chloride precursors. Activation of these gold(I) carbenoids with a variety of chloride scavengers promotes reactivity typical of metallocarbenes in solution, namely homocoupling to ethylene, olefin cyclopropanation, and Buchner ring expansion of benzene
Gold(I) complexes with N-heterocyclic carbene ligands functionalized with a pendant phosphonium moie...
Historically, chemists have been motivated by problems in total synthesis or by a desire to develop ...
A new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH...
Chloromethylgold(I) complexes of phosphine, phosphite, and N-heterocyclic carbene ligands are easily...
The discovery of sustainable and scalable synthetic protocols leading to gold-aryl compounds bearing...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
In recent years, gold(I) complexes have seen increased use as catalysts for the activation of alkyne...
A series of ligated gold(I) carbenes (where the ligand is Ph<sub>3</sub>P, Me<sub>2</sub>S, or an N...
A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use o...
cyclopropenes; gold carbenes; gold catalysis; gold-stabilized allylic cations; ring-openin
The different coordination modes in carbon-gold(I) complexes are spotlighted with a focus on gold(I)...
We present herein, a series of N-heterocyclic carbene gold(I) complexes derived from (1,3-dibenzyl-4...
This review considers phosphine and N-heterocyclic carbene complexes of gold(I) that are used as (pr...
A series of propargyl functionalized N-heterocyclic carbene gold(I) complexes have been synthesized ...
Gold(I) complexes with N-heterocyclic carbene ligands functionalized with a pendant phosphonium moie...
Historically, chemists have been motivated by problems in total synthesis or by a desire to develop ...
A new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH...
Chloromethylgold(I) complexes of phosphine, phosphite, and N-heterocyclic carbene ligands are easily...
The discovery of sustainable and scalable synthetic protocols leading to gold-aryl compounds bearing...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
Gold has emerged as a powerful synthetic tool in the chemist's arsenal. From the early use of inorga...
In recent years, gold(I) complexes have seen increased use as catalysts for the activation of alkyne...
A series of ligated gold(I) carbenes (where the ligand is Ph<sub>3</sub>P, Me<sub>2</sub>S, or an N...
A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use o...
cyclopropenes; gold carbenes; gold catalysis; gold-stabilized allylic cations; ring-openin
The different coordination modes in carbon-gold(I) complexes are spotlighted with a focus on gold(I)...
We present herein, a series of N-heterocyclic carbene gold(I) complexes derived from (1,3-dibenzyl-4...
This review considers phosphine and N-heterocyclic carbene complexes of gold(I) that are used as (pr...
A series of propargyl functionalized N-heterocyclic carbene gold(I) complexes have been synthesized ...
Gold(I) complexes with N-heterocyclic carbene ligands functionalized with a pendant phosphonium moie...
Historically, chemists have been motivated by problems in total synthesis or by a desire to develop ...
A new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH...