The total synthesis of lundurines A–C has been accomplished in racemic and enantiopure forms in 11–13 and 12–14 steps, respectively, without protection/deprotection of functional groups, by a novel tandem double condensation/Claisen rearrangement, a gold(I)-catalyzed alkyne hydroarylation, a cyclopropanation via formal [3 + 2] cycloaddition/nitrogen extrusion, and a remarkable olefin migration through a vinylcyclopropane retro-ene/ene reaction that streamlines the endgame
1,6-Enynes bearing OR groups at the propargyl position generate a,b-unsaturated gold(I)-carbenes/ go...
International audienceThe gold(I) catalyzed rearrangement of 5-en-2-yn-1-yl acetates into functional...
MasterThe catalysis of organic reactions mediated by transition metals has become an essential tool ...
The total synthesis of lundurines A–C has been accomplished in racemic and enantiopure forms in 11–1...
The total synthesis of lundurines A–C has been accomplished in racemic and enantiopure forms in 11–1...
A total synthesis of (±)-lundurine B was accomplished. A combination of stereoselective intramolecul...
The total synthesis of seven members of the lapidilectine and grandilodine family of alkaloids has b...
The total synthesis of seven members of the lapidilectine and grandilodine family of alkaloids has b...
Recent advances in transition metal catalyzed C-H activation are revolutionizing synthetic organic c...
The formal (3+2) cycloaddition between terminal allenes and aryl or styryl gold(I) carbenes generate...
En esta Tesis Doctoral se realiza un estudio detallado de la reacción inter- e intramolecular de com...
Over the years, gold catalysis has materialized as an incredible synthetic approach among the scient...
Asymmetric synthesis plays a critical role in the synthesis of modern pharmaceutical compounds which...
An efficient formal total synthesis of (+/-)-clavukerin A was accomplished via a gold-catalyzed cycl...
Novel organic reactions drive the advance of chemical synthesis in the same way that enabling techno...
1,6-Enynes bearing OR groups at the propargyl position generate a,b-unsaturated gold(I)-carbenes/ go...
International audienceThe gold(I) catalyzed rearrangement of 5-en-2-yn-1-yl acetates into functional...
MasterThe catalysis of organic reactions mediated by transition metals has become an essential tool ...
The total synthesis of lundurines A–C has been accomplished in racemic and enantiopure forms in 11–1...
The total synthesis of lundurines A–C has been accomplished in racemic and enantiopure forms in 11–1...
A total synthesis of (±)-lundurine B was accomplished. A combination of stereoselective intramolecul...
The total synthesis of seven members of the lapidilectine and grandilodine family of alkaloids has b...
The total synthesis of seven members of the lapidilectine and grandilodine family of alkaloids has b...
Recent advances in transition metal catalyzed C-H activation are revolutionizing synthetic organic c...
The formal (3+2) cycloaddition between terminal allenes and aryl or styryl gold(I) carbenes generate...
En esta Tesis Doctoral se realiza un estudio detallado de la reacción inter- e intramolecular de com...
Over the years, gold catalysis has materialized as an incredible synthetic approach among the scient...
Asymmetric synthesis plays a critical role in the synthesis of modern pharmaceutical compounds which...
An efficient formal total synthesis of (+/-)-clavukerin A was accomplished via a gold-catalyzed cycl...
Novel organic reactions drive the advance of chemical synthesis in the same way that enabling techno...
1,6-Enynes bearing OR groups at the propargyl position generate a,b-unsaturated gold(I)-carbenes/ go...
International audienceThe gold(I) catalyzed rearrangement of 5-en-2-yn-1-yl acetates into functional...
MasterThe catalysis of organic reactions mediated by transition metals has become an essential tool ...