This work focuses on catalysing the hydrolysis of DNA-like substrate with mononuclear zinc complexes. Particular attention is given to find new ways of activating the nucleophile of the reaction and to study the impact of organic groups that affect the microenvironment of the metal ion
The hydrolytic activity of the 1,3,5-triaminocycloxexane derivatives TACH, TACI and TMCA complexed t...
The hydrolytic ability toward plasmid DNA of a mononuclear and a binuclear Zn(II) complex with two m...
The dinuclear complex [Zn2(DPCPMP)(pivalate)](ClO4), where DPCPMP is the new unsymmetrical ligand [2...
The design of artificial catalysts to hydrolyse phosphate diesters under mild conditions remains ext...
The development of synthetic agents able to hydrolytically cleave phosphate diester bonds with high ...
The development of synthetic agents able to hydrolytically cleave phosphate diester bonds with high ...
The dinuclear ligand 1 based on the bis-(2-amino-pyridinyl-6-methyl)amine (BAPA) metal binding unit ...
Creating efficient artificial catalysts that can compete with biocatalysis has been an enduring chal...
Phosphate esters are essential to any living organism and their specific hydrolysis plays an importa...
A novel binuclear zinc complex has been synthesized. The complex is highly efficient in the hydrolys...
The design of artificial catalysts to hydrolyse phosphate diesters under mild conditions remains ext...
Although natural systems demonstrate that simple organic features and metal ion cofactors can combin...
The hydrolytic activity of the 1,3,5-triaminocycloxexane derivatives TACH, TACI and TMCA complexed t...
The catalytic effects of the Zn(II) complexes of a series of poliaminic ligands in the hydrolysis of...
Density functional theory calculations have been used to investigate the reaction mechanisms of phos...
The hydrolytic activity of the 1,3,5-triaminocycloxexane derivatives TACH, TACI and TMCA complexed t...
The hydrolytic ability toward plasmid DNA of a mononuclear and a binuclear Zn(II) complex with two m...
The dinuclear complex [Zn2(DPCPMP)(pivalate)](ClO4), where DPCPMP is the new unsymmetrical ligand [2...
The design of artificial catalysts to hydrolyse phosphate diesters under mild conditions remains ext...
The development of synthetic agents able to hydrolytically cleave phosphate diester bonds with high ...
The development of synthetic agents able to hydrolytically cleave phosphate diester bonds with high ...
The dinuclear ligand 1 based on the bis-(2-amino-pyridinyl-6-methyl)amine (BAPA) metal binding unit ...
Creating efficient artificial catalysts that can compete with biocatalysis has been an enduring chal...
Phosphate esters are essential to any living organism and their specific hydrolysis plays an importa...
A novel binuclear zinc complex has been synthesized. The complex is highly efficient in the hydrolys...
The design of artificial catalysts to hydrolyse phosphate diesters under mild conditions remains ext...
Although natural systems demonstrate that simple organic features and metal ion cofactors can combin...
The hydrolytic activity of the 1,3,5-triaminocycloxexane derivatives TACH, TACI and TMCA complexed t...
The catalytic effects of the Zn(II) complexes of a series of poliaminic ligands in the hydrolysis of...
Density functional theory calculations have been used to investigate the reaction mechanisms of phos...
The hydrolytic activity of the 1,3,5-triaminocycloxexane derivatives TACH, TACI and TMCA complexed t...
The hydrolytic ability toward plasmid DNA of a mononuclear and a binuclear Zn(II) complex with two m...
The dinuclear complex [Zn2(DPCPMP)(pivalate)](ClO4), where DPCPMP is the new unsymmetrical ligand [2...