Development of a glass-ceramic glaze formulated from industrial residues to improve the mechanical properties of the porcelain stoneware tiles

In this research a mixture of 90%wt of industrial residues (recycled soda-lime glass and ashes from a coalpower thermal plant) have been vitrified for their use as ‘‘secondary raw material”. Then, a glaze suspen-sion was prepared to be applied on the porcelain stoneware tile. The tested pieces have been fired by aconventional porcelain cycle at 1180 °C of maximum temperature. The XRD, XRF, SEM/EDS and thedilatometric analysis have been the instrumental techniques used to characterize the material. Finally,an ecological glass-ceramic glaze perfectly fitting on porcelain ceramic tile has been produced, exhibitinga unique phase, anorthite, which ensures a high flexural strength (around 96 MPa) and a significantVickers microhardness of 250 GPa, improving the mechanical properties of a conventional the porcelainceramic tile