Add to ORKG© 2019, Pleiades Publishing, Ltd. Abstract: The reaction of uranyl nitrate with the [P8W48O184]40– polylacunary polyanion gives the [(UO2)7P8W48O184]26– (1) and [(UO2)8P8W48O184]24– (2) anions, which were isolated as potassium and ammonium salts. For K24[(UO2)8P8W48O184] · 50H2O · 3LiCl and (NH4)16H8[(UO2)8P8W48O184] · 50H2O, X-ray diffraction study was performed. The incorporation of uranyl ions into [P8W48O184]40– was confirmed by IR and Raman spectroscopy and by mass spectrometry. Electrochemical study of 2 indicated the possibility of uranium reduction to U(IV). X-ray luminescence of the potassium salts of 1 and 2 was investigated
The work detailed in this thesis is presented and discussed in three distinct chapters, which consti...
The most common motif in uranium chemistry is the linear d0f0 uranyl ion [UO2]2+. The strong, covale...
The use of B-α-[AsW9O33]9-anionic moieties in association with the tetravalent 5f uranium UCl4 precu...
© 2019, Pleiades Publishing, Ltd. Abstract: The reaction of uranyl nitrate with the [P8W48O184]40– p...
La recherche de molécules permettant l’extraction et la stabilisation d’actinides est un sujet majeu...
Association of uranyl nitrate with the macrocycle [P8W48O184]40– in formate buffered aqueous solutio...
The synthesis, reactivity, structures, and bonding in gas-phase binary and complex oxide anion molec...
The synthesis, reactivity, structures, and bonding in gas-phase binary and complex oxide anion molec...
A ring-shaped polyoxometalate (POM), [P8W48O184]40– (P8W48), formed by condensation of four hexavaca...
The uranyl triperoxide anionic monomer is a fundamental building block for uranyl peroxide polyoxome...
Addition of 2 equiv of Ph3COH to UO2[NR2]2(THF)2 (R = SiMe3) generates the U(VI) bis-alkoxide comple...
Three new compounds, (GuaH)4[W10O32](H2O)4 (1), (ThbH)3(H3O)[(W10O32](H2O)7.5 (2) and (ThbH)2[W6O19]...
A novel uranium heteropolyoxometalate, [H<sub>3</sub>O]<sub>4</sub>[Ni(H<sub>2</sub>O)<sub>3</sub>]...
One of the biggest challenges in chemistry is the selective synthesis of molecular structures in a c...
Herein, we report a new salt of a pyrophosphate-functionalized uranyl peroxide nanocluster {U<sub>24...
The work detailed in this thesis is presented and discussed in three distinct chapters, which consti...
The most common motif in uranium chemistry is the linear d0f0 uranyl ion [UO2]2+. The strong, covale...
The use of B-α-[AsW9O33]9-anionic moieties in association with the tetravalent 5f uranium UCl4 precu...
© 2019, Pleiades Publishing, Ltd. Abstract: The reaction of uranyl nitrate with the [P8W48O184]40– p...
La recherche de molécules permettant l’extraction et la stabilisation d’actinides est un sujet majeu...
Association of uranyl nitrate with the macrocycle [P8W48O184]40– in formate buffered aqueous solutio...
The synthesis, reactivity, structures, and bonding in gas-phase binary and complex oxide anion molec...
The synthesis, reactivity, structures, and bonding in gas-phase binary and complex oxide anion molec...
A ring-shaped polyoxometalate (POM), [P8W48O184]40– (P8W48), formed by condensation of four hexavaca...
The uranyl triperoxide anionic monomer is a fundamental building block for uranyl peroxide polyoxome...
Addition of 2 equiv of Ph3COH to UO2[NR2]2(THF)2 (R = SiMe3) generates the U(VI) bis-alkoxide comple...
Three new compounds, (GuaH)4[W10O32](H2O)4 (1), (ThbH)3(H3O)[(W10O32](H2O)7.5 (2) and (ThbH)2[W6O19]...
A novel uranium heteropolyoxometalate, [H<sub>3</sub>O]<sub>4</sub>[Ni(H<sub>2</sub>O)<sub>3</sub>]...
One of the biggest challenges in chemistry is the selective synthesis of molecular structures in a c...
Herein, we report a new salt of a pyrophosphate-functionalized uranyl peroxide nanocluster {U<sub>24...
The work detailed in this thesis is presented and discussed in three distinct chapters, which consti...
The most common motif in uranium chemistry is the linear d0f0 uranyl ion [UO2]2+. The strong, covale...
The use of B-α-[AsW9O33]9-anionic moieties in association with the tetravalent 5f uranium UCl4 precu...