Add to ORKGReactions of trialkyl phosphates and dialkyl alkenylphosphonates with trichloro(o-phenylenedioxy)phosphorane result in selective replacement of one alkoxy group on the phosphorus by a chlorine atom. Alkylphosphonates react with trichloro(o-phenylenedioxy)phosphorane to give alkyl alkylphosphonochloridates as the major products and small amounts of alkylphosphonic dichlorides
The reaction of (OCH2CMe2CH2O)P(O)Cl (1)with 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) afforded the p...
1. The addition of trialkyl phosphites to α, β-unsaturated acids can proceed via the prior protoniza...
International audienceDiethyl 1,1-dichloromethylphosphonate (2) was synthesised in good yield from t...
Reactions of trialkyl phosphates and dialkyl alkenylphosphonates with trichloro(o-phenylenedioxy)pho...
Trichloro(o-phenylenedioxy)phosphorane reacts with 1,2-alkadienylphosphonates with selective replace...
International audienceThis review deals with the phosphonate–phosphonochloridate conversion. The dif...
The reactions of the trichloroacetamide derivatives, Cl₃CCONHY where Y = CONH₂, CONMe₂ , COCH₂Cl, CS...
1. When three molecules ef the ethyl ester of orthopropionic acid were reacted with one of phosphoru...
The reactions of trivalent phosphorus esters, including trialkyl phosphites, dialkyl phosphonites, a...
© 2014 Taylor & Francis Group, LLC. The reactions of trivalent phosphorus esters, including trialkyl...
Treatment of PCl3 with o-HOC6H4COCH2R (R = H or Et) and NEt3 affords 2-chloro-1,3,2-dioxaphosphorina...
Reaction of commercially available trialkyl phosphites with N-phthalylamino acids gave mixtures of s...
For the first time, stable pentaalkoxyspirophosphoranes were isolated in addition to phosphoranes wi...
The majority of this project is to discover novel mechanistic pathways for a wide range of organic r...
1. Hydrochlorides of amino acid chlorides react with triethyl phosphite with formation of the hydroc...
The reaction of (OCH2CMe2CH2O)P(O)Cl (1)with 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) afforded the p...
1. The addition of trialkyl phosphites to α, β-unsaturated acids can proceed via the prior protoniza...
International audienceDiethyl 1,1-dichloromethylphosphonate (2) was synthesised in good yield from t...
Reactions of trialkyl phosphates and dialkyl alkenylphosphonates with trichloro(o-phenylenedioxy)pho...
Trichloro(o-phenylenedioxy)phosphorane reacts with 1,2-alkadienylphosphonates with selective replace...
International audienceThis review deals with the phosphonate–phosphonochloridate conversion. The dif...
The reactions of the trichloroacetamide derivatives, Cl₃CCONHY where Y = CONH₂, CONMe₂ , COCH₂Cl, CS...
1. When three molecules ef the ethyl ester of orthopropionic acid were reacted with one of phosphoru...
The reactions of trivalent phosphorus esters, including trialkyl phosphites, dialkyl phosphonites, a...
© 2014 Taylor & Francis Group, LLC. The reactions of trivalent phosphorus esters, including trialkyl...
Treatment of PCl3 with o-HOC6H4COCH2R (R = H or Et) and NEt3 affords 2-chloro-1,3,2-dioxaphosphorina...
Reaction of commercially available trialkyl phosphites with N-phthalylamino acids gave mixtures of s...
For the first time, stable pentaalkoxyspirophosphoranes were isolated in addition to phosphoranes wi...
The majority of this project is to discover novel mechanistic pathways for a wide range of organic r...
1. Hydrochlorides of amino acid chlorides react with triethyl phosphite with formation of the hydroc...
The reaction of (OCH2CMe2CH2O)P(O)Cl (1)with 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) afforded the p...
1. The addition of trialkyl phosphites to α, β-unsaturated acids can proceed via the prior protoniza...
International audienceDiethyl 1,1-dichloromethylphosphonate (2) was synthesised in good yield from t...