Add to ORKGThe structure of 5,11,17,23-tetra-tert-butyl-25,27-dihydroxy-26,28-bis[N- (4′-nitrophenyl)aminocarbonylmethoxy] thiacalix[4]arene I was examined by 1D and 2D (NOESY) 1H and 13C NMR methods in a CDCl 3 solution using numerical simulation (semi-empirical quantum-chemical calculations, PM3 method). Compound I was found to exist in the 1,2-alternate conformation, where bulky substituents OCH2C(O) · NHPhNO2 are in the endo-position relative to the macrocycle cavity. © 2013 Pleiades Publishing, Ltd
Calix[n]arenes and their derivatives are often used in supramolecular chemistry for their pronounced...
Direct O-alkylation of p-tert-butyldihomooxacalix[4]arene (1) with 2-(chloromethyl)pyridine hydrochl...
The possibility of using an approach for the elucidation of the spatial structure of functionalized ...
The structure of 5,11,17,23-tetra-tert-butyl-25,27-dihydroxy-26,28-bis[N- (4′-nitrophenyl)aminocarbo...
Structures of 5,11,17,23-tetra-tert-butyl-25,26,27-trihydroxy-28- and 5,11,17,23-tetra-tert-butyl-25...
The structure of three isomers of 5,11,17,23-tetra-t-butyl-25,26,27,28- tetrakis[(morpholidocarbonyl...
New derivatives of p-tert-butylthiacalix[4]arene were synthesized. The conformation of the macrocycl...
It is demonstrated that dissolution of aminothiacalix[4]arene in chloroform results in transformatio...
It is demonstrated that the introduction of p-tert-butyl groups dramatically influences the conforma...
New organosilicon derivatives of p-tert-butylthiacalix[4]arene with one or two ring fragments at the...
© 2015 Pleiades Publishing, Ltd. Lower-rim substituted bis- and tetrakis(alkynyloxy)thiacalix[4]aren...
Calix[n]arenes and their derivatives are often used in supramolecular chemistry for their pronounced...
Direct O-alkylation of p-tert-butyldihomooxacalix[4]arene (1) with 2-(chloromethyl)pyridine hydrochl...
The possibility of using an approach for the elucidation of the spatial structure of functionalized ...
The structure of 5,11,17,23-tetra-tert-butyl-25,27-dihydroxy-26,28-bis[N- (4′-nitrophenyl)aminocarbo...
Structures of 5,11,17,23-tetra-tert-butyl-25,26,27-trihydroxy-28- and 5,11,17,23-tetra-tert-butyl-25...
The structure of three isomers of 5,11,17,23-tetra-t-butyl-25,26,27,28- tetrakis[(morpholidocarbonyl...
New derivatives of p-tert-butylthiacalix[4]arene were synthesized. The conformation of the macrocycl...
It is demonstrated that dissolution of aminothiacalix[4]arene in chloroform results in transformatio...
It is demonstrated that the introduction of p-tert-butyl groups dramatically influences the conforma...
New organosilicon derivatives of p-tert-butylthiacalix[4]arene with one or two ring fragments at the...
© 2015 Pleiades Publishing, Ltd. Lower-rim substituted bis- and tetrakis(alkynyloxy)thiacalix[4]aren...
Calix[n]arenes and their derivatives are often used in supramolecular chemistry for their pronounced...
Direct O-alkylation of p-tert-butyldihomooxacalix[4]arene (1) with 2-(chloromethyl)pyridine hydrochl...
The possibility of using an approach for the elucidation of the spatial structure of functionalized ...