Integrated analytical techniques for the characterization of repainted wooden statues dated to the fifteenth century

The polychrome wooden sculpture is a complex artifact because of the presence of different materials and techniques. Due to changes in style or decay, objects closely related to the cult were often over painted. The present study aim to identify and set-up a correct investigation methodology to identify pigments and binders of the original layer and subsequent overpaintings that often characterize polychrome wooden sculptures, pointing out how the acquisition of these data can be a support not only to the activity of the restorer, who frequently has to face the removal of the overlayers, but also to the deepening of the historical artistic context, connected to the knowledge of the work of art. In this particular study a multi-analytical approach has been applied on two fifteenth-century Ligurian Christs, the first one from San Bartolomeo parish in Zuccarello, the second from Borghetto San Nicol\uf2, both heavily rehashed. The application of different analytical techniques is in fact often successfully for paints analysis. By comparing the results of XRF analysis performed with portable instrumentation on stratigraphic sequences related to samples coming from different color areas of the work, with the data obtained by SEM-EDS, the inert of the different layers could be identified, then confirmed by \u3bc-FTIR that also revealed the chemical nature of the binders employed in the different overpaintings, later confirmed and identified by GC-MS analysis. The study has allowed a new possibility of comparison, based on analytical data, in the classification system of the " selva dei Cristi feriti liguri quattrocenteschi nel Ponente", of which the two works are part, proposed in the text "La Sacra Selva. Scultura lignea in Liguria tra XII e XVI secolo "