Add to ORKGIntramolecular structural relaxations occurring upon electron transfer are crucial in determining the rate of redox reactions. Here, we demonstrate that subangstrom structural changes occurring upon single-electron charging can be quantified by means of atomically resolved atomic force microscopy (AFM) for the case of single copper(II)phthalocyanine (CuPc) molecules deposited on an ultrathin NaCl film. Imaging the molecule in distinct charge states (neutral and anionic) reveals characteristic differences in the AFM contrast. In comparison to density functional theory simulations these changes in contrast can be directly related to relaxations of the molecule's geometric structure upon charging. The dominant contribution arises from a nonhom...
The forces governing the contrast in submolecular resolution imaging of molecules with atomic force ...
Kelvin probe force spectroscopy was used to characterize the charge distribution of individual molec...
In scanning probe microscopy, the imaging characteristics in the various interaction channels crucia...
Intramolecular structural relaxations occurring upon electron transfer are crucial in determining th...
In this thesis, structural and electronic effects accompanying electron transfer reactions in indivi...
Intermolecular single-electron transfer on electrically insulating films is a key process in molecul...
How electronic charge is distributed over a molecule determines to a large extent its chemical prope...
Copper phthalocyanine (CuPc) is a small molecule often used in organic light emitting diodes where i...
International audienceScanning tunneling microscopy and dynamic force microscopy in the noncontact m...
Charge states of atoms can be investigated with scanning tunneling microscopy, but this method requi...
Charge states of atoms can be investigated with scanning tunneling microscopy, but this method requi...
In this thesis work, a combination of low-temperature scanning tunneling microscopy (STM) and atomic...
| openaire: EC/FP7/610446/EU//PAMSSingle Sn-phthalocyanine (SnPc) molecules adsorb on Cu(1 0 0) with...
International audienceThe use of molecular materials in solar cells and nano-electronics demands a f...
The forces governing the contrast in submolecular resolution imaging of molecules with atomic force ...
Kelvin probe force spectroscopy was used to characterize the charge distribution of individual molec...
In scanning probe microscopy, the imaging characteristics in the various interaction channels crucia...
Intramolecular structural relaxations occurring upon electron transfer are crucial in determining th...
In this thesis, structural and electronic effects accompanying electron transfer reactions in indivi...
Intermolecular single-electron transfer on electrically insulating films is a key process in molecul...
How electronic charge is distributed over a molecule determines to a large extent its chemical prope...
Copper phthalocyanine (CuPc) is a small molecule often used in organic light emitting diodes where i...
International audienceScanning tunneling microscopy and dynamic force microscopy in the noncontact m...
Charge states of atoms can be investigated with scanning tunneling microscopy, but this method requi...
Charge states of atoms can be investigated with scanning tunneling microscopy, but this method requi...
In this thesis work, a combination of low-temperature scanning tunneling microscopy (STM) and atomic...
| openaire: EC/FP7/610446/EU//PAMSSingle Sn-phthalocyanine (SnPc) molecules adsorb on Cu(1 0 0) with...
International audienceThe use of molecular materials in solar cells and nano-electronics demands a f...
The forces governing the contrast in submolecular resolution imaging of molecules with atomic force ...
Kelvin probe force spectroscopy was used to characterize the charge distribution of individual molec...
In scanning probe microscopy, the imaging characteristics in the various interaction channels crucia...