The mechanism of self-assembly of a polynuclear complex of a [4 + 4] Schiff base iminomethylenediphenolate macrocycle [BaCu4(4 + 4)]2+ via a non-macrocyclic dialdehyde intermediate has been followed using ESI-MS of the reaction solutions. Both assembly of the intermediate and Schiffbase condensation with diamine give rise to single products; formation of the intermediate metallacycle is fast but Schiffbase condensation ismuch slower. Both intermediate complex andmacrocyclic product have been structurally characterised
Two remote dialkylaluminium centres supported by a macrocyclic Schiff base ligand exhibited benefici...
Reaction of the [2 + 2] Schiff-base macrocycles {[2-(OH)-5-(R)-C6H2-1,3-(CH)2][CH2CH2(2-C6H4N)2]}2(R...
Two remote dialkylaluminium centres supported by a macrocyclic Schiff base ligand exhibited benefici...
Schiff-base macrocycles have interesting properties that could be used in new materials such as chem...
The classical formaldehyde building block has been replaced by the bulkier benzaldehyde in the CuII ...
This thesis describes the synthesis, characterization, and host-guest studies of a series of Schiff-...
The [3+3] Schiff-base macrocycles (37-40) were obtained by reacting 3,6- diformyl-l,2-dihydroxybenze...
866-870A set of hitherto unreported 13- to 20-membered Schiff base macrocycles have been synthesize...
The anion-templated synthesis of different pseudopeptidic macrocycles has been studied in detail by ...
Two 46-membered [2 + 2] Schiff-base macrocyclic dinuclear Zn(II) complexes (<b>1a</b> and <b>1b</b>...
Conjugated Schiff-base macrocycles are interesting compounds of interest as platforms for catalysis,...
Diethylmalonate acts as an efficient locking fragment in the CuII directed synthesis of 14-membered ...
The condensation of aromatic dialdehydes with chiral diamines, such as 1,2-trans-diaminocyclohexane,...
A macrocyclic ligand has been synthesized by reaction of 2,6-diaminopyridine and 1,6-bis(2-formylphe...
A series of conjugated [3+3] Schiff-base macrocycles containing both a central crown ether-like poc...
Two remote dialkylaluminium centres supported by a macrocyclic Schiff base ligand exhibited benefici...
Reaction of the [2 + 2] Schiff-base macrocycles {[2-(OH)-5-(R)-C6H2-1,3-(CH)2][CH2CH2(2-C6H4N)2]}2(R...
Two remote dialkylaluminium centres supported by a macrocyclic Schiff base ligand exhibited benefici...
Schiff-base macrocycles have interesting properties that could be used in new materials such as chem...
The classical formaldehyde building block has been replaced by the bulkier benzaldehyde in the CuII ...
This thesis describes the synthesis, characterization, and host-guest studies of a series of Schiff-...
The [3+3] Schiff-base macrocycles (37-40) were obtained by reacting 3,6- diformyl-l,2-dihydroxybenze...
866-870A set of hitherto unreported 13- to 20-membered Schiff base macrocycles have been synthesize...
The anion-templated synthesis of different pseudopeptidic macrocycles has been studied in detail by ...
Two 46-membered [2 + 2] Schiff-base macrocyclic dinuclear Zn(II) complexes (<b>1a</b> and <b>1b</b>...
Conjugated Schiff-base macrocycles are interesting compounds of interest as platforms for catalysis,...
Diethylmalonate acts as an efficient locking fragment in the CuII directed synthesis of 14-membered ...
The condensation of aromatic dialdehydes with chiral diamines, such as 1,2-trans-diaminocyclohexane,...
A macrocyclic ligand has been synthesized by reaction of 2,6-diaminopyridine and 1,6-bis(2-formylphe...
A series of conjugated [3+3] Schiff-base macrocycles containing both a central crown ether-like poc...
Two remote dialkylaluminium centres supported by a macrocyclic Schiff base ligand exhibited benefici...
Reaction of the [2 + 2] Schiff-base macrocycles {[2-(OH)-5-(R)-C6H2-1,3-(CH)2][CH2CH2(2-C6H4N)2]}2(R...
Two remote dialkylaluminium centres supported by a macrocyclic Schiff base ligand exhibited benefici...