Modelling, thermoeconomic analysis and optimization of hybrid solar-biomass organic Rankine cycle power plants

The need for modern energy systems to embrace the requirements of energy security, sustainability and affordability in their designs has placed emphatic importance on exploitation of renewable resources, such as solar and wind energy, etc. However, these resources often lead to reduced reliability and dispatchability of energy systems; less-efficient conversion processes; high cost of power production; etc. One promising way to ameliorate these challenges is through hybridization of renewable energy resources, and by using organic Rankine cycle (ORC) for power generation. Thus, this PhD research project is aimed at conceptual design and techno-economic optimization of hybrid solar-biomass ORC power plants. The methodologies adopted are in four distinct phases: - First, novel hybrid concentrated solar power (CSP)-biomass scheme was conceived that could function as retrofit to existing CSP-ORC plants as well as in new hybrid plant designs. Thermodynamic models were developed for each plant sub-unit, and yearly techno-economic performance was assessed for the entire system. Specifically, the ORC was modelled based on characteristics of an existing CSP-ORC plant, which currently operates at Ottana, Italy. Off-design models of ORC components were integrated, and their performance was validated using experimental data obtained from the aforementioned real plant. - Second, detailed exergy and exergoeconomic analyses were performed on the proposed hybrid plant, in order to examine the system components with remarkable optimization potentials. The evaluation on optimization potentials considered intrinsic irreversibilities in the respective components, which are imposed by assumptions of systemic and economic constraints. This has been termed enhanced exergy and enhanced exergoeconomic analyses here. - Third, the techno-economic implications of using siloxane mixtures as ORC working fluid were investigated, with the aim of improving heat transfer processes in the ORC plant. The studied fluid pairs were actively selected to satisfy classical thermodynamic requirements, based on established criteria. - Fourth, the biomass retrofit system was optimized multi-objectively, to minimize biomass consumption rate (maximize exergetic efficiency) and to minimize exergy cost rate. Non-dominated Sorting Genetic Algorithm (NSGA-II) was adopted for multi-objective optimization. The conceptual scheme involves parallel hybridization of CSP and biomass systems, such that each is capable of feeding the ORC directly. Results showed that the proposed biomass hybridization concept would increase both thermodynamic efficiency and economic performance of CSP-ORC plants, thereby improving their market competitiveness. Total exergy destroyed and exergy efficiency were quantified for each component, and for the whole system. Overall system exergetic efficiency of about 7 % was obtained. Similarly, exergoeconomic factor was obtained for each system component, and their implications were analysed to identify system components with high potentials for optimization. Furthermore, it was observed that thermodynamic performance of the hybrid plant would be optimized by using siloxane mixtures as ORC working fluid. However, this would result in larger heat exchange surface area, with its attendant cost implications. Lastly, biomass combustion and furnace parameters were obtained, which would simultaneously optimize exergetic efficiency and exergy cost rate for the hybrid plant. In sum, a novel scheme has been developed for hybridizing solar and biomass energy for ORC plants, with huge potentials to improve techno-economic competitiveness of solar-ORC systems