Superconductivity in the η-carbide-type oxides Zr4Rh2Ox

We report on the synthesis and the superconductivity in (x = 0.4, 0.5, 0.6, 0.7, 1.0). These compounds crystallize in the η-carbide structure, which is a filled version of the complex intermetallic structure. We find that in the system , already a small amount (x 0.4) of oxygen addition stabilizes the η-carbide structure over the more common intermetallic structure-type, in which crystallizes. We show that and are bulk superconductors with critical temperatures of 2.8 K and 4.7 K in the resistivity, respectively. Our analysis of the superconducting properties reveal both compounds to be strongly type-II superconductors with critical fields up to (0) 8.8 mT and (0) 6.08 T. Our results support that the η-carbides are a versatile family of compounds for the investigation of the interplay of interstitial doping on physical properties, especially for superconductivity