Advanced graphene-based transparent conductive electrodes for photovoltaic applications

New architectures of transparent conductive electrodes (TCEs) incorporating graphene monolayers in different configurations have been explored with the aim to improve the performance of silicon-heterojunction (SHJ) cell front transparent contacts. In SHJ technology, front electrodes play an important additional role as anti-reflectance (AR) coatings. In this work, different transparent-conductive-oxide (TCO) thin films have been combined with graphene monolayers in different configurations, yielding advanced transparent electrodes specifically designed to minimize surface reflection over a wide range of wavelengths and angles of incidence and to improve electrical performance. A preliminary analysis reveals a strong dependence of the optoelectronic properties of the TCEs on (i) the order in which the different thin films are deposited or the graphene is transferred and (ii) the specific TCO material used. The results shows a clear electrical improvement when three graphene monolayers are placed on top on 80-nm-thick ITO thin film. This optimum TCE presents sheet resistances as low as 55 Ω/sq and an average conductance as high as 13.12 mS. In addition, the spectral reflectance of this TCE also shows an important reduction in its weighted reflectance value of 2-3%. Hence, the work undergone so far clearly suggests the possibility to noticeably improve transparent electrodes with this approach and therefore to further enhance silicon-heterojunction cell performance. These results achieved so far clearly open the possibility to noticeably improve TCEs and therefore to further enhance SHJ contact-technology performance.This research was partially funded by the Spanish Ministry of Science & Innovation under the project DIGRAFEN, grant number (ENE2017-88065-C2-1-R) and (ENE2017-88065-C2-2-R). J.P. acknowledges support from Spanish MINECO (Grant RyC-2015-18968). R.S.F. acknowledges support from European Union’s Horizon 2020 Research and Innovation Programme under Marie Sklodowska-Curie Grant Agreement No 642688. M.A.P. acknowledges support from Spanish MINECO (Grant FJCI-2016-29146)