Sensitivity of the Mott transition to noncubic splitting of the orbital degeneracy: Application to NH3K3C60

Within dynamical mean-field theory, we study the metal-insulator transition of a twofold orbitally degenerate Hubbard model as a function of a splitting Delta of the degeneracy. The phase diagram in the U-Delta plane exhibits two-band and one-band metals, as well as the Mott insulator. The correlated two-band metal is easily driven to the insulator state by a strikingly weak splitting Delt