A strategy for expedient synthesis of 3-substituted chromones from easily available o-hydroxyarylenaminones and diazo compounds has been developed. Carefully conducted experimental and computational studies led us to propose an uncommon mechanistic pathway involving the hydroxyl group assisted alkylation of enaminones with in situ generated gold carbenes. © 2018 American Chemical Societ
none6noThe site-selective a-allylic alkylation of enones with alcohols via gold-triggered formation ...
The advent of gold catalysis has transformed hydroxyalkoxylation of alkynes - once a rudimentary, me...
DoctorThe addition reaction to a carbon-carbon multiple bond in a catalytic version is one of the mo...
A strategy for expedient synthesis of 3-substituted chromones from easily available o-hydroxyarylen...
F or the past dozen years, homogeneous gold catalysis has evolved from a little known topic in organ...
International audienceUsing easily accessible aromatic alkoxy-arylalkynones, we have investigated th...
Recent years have witnessed a tremendous growth in the number of gold-catalyzed highly selective che...
Golden touch: Gold?catalyzed reaction of N?sulfonyl hydroxylamines with terminal alkyne led to 3?pyr...
Despite the tremendous advance in homogeneous gold catalysis in the past decade or so, the functiona...
The discovery of sustainable and scalable synthetic protocols leading to gold-aryl compounds bearing...
For the past dozen years, homogeneous gold catalysis has evolved from a little known topic in organi...
Recently established as an excellent activator for π-systems, efforts made in gold chemistry have in...
In Chapter 2, a gold-catalyzed domino annulation of diazo-tethered alkynes with nitriles proceeds th...
<p><p>The wide-spread occurrence of biologically active nitrogen-containing heterocycles and allylic...
A novel gold-catalyzed water-mediated carbene cascade reaction of propargyl diazoacetates has been d...
none6noThe site-selective a-allylic alkylation of enones with alcohols via gold-triggered formation ...
The advent of gold catalysis has transformed hydroxyalkoxylation of alkynes - once a rudimentary, me...
DoctorThe addition reaction to a carbon-carbon multiple bond in a catalytic version is one of the mo...
A strategy for expedient synthesis of 3-substituted chromones from easily available o-hydroxyarylen...
F or the past dozen years, homogeneous gold catalysis has evolved from a little known topic in organ...
International audienceUsing easily accessible aromatic alkoxy-arylalkynones, we have investigated th...
Recent years have witnessed a tremendous growth in the number of gold-catalyzed highly selective che...
Golden touch: Gold?catalyzed reaction of N?sulfonyl hydroxylamines with terminal alkyne led to 3?pyr...
Despite the tremendous advance in homogeneous gold catalysis in the past decade or so, the functiona...
The discovery of sustainable and scalable synthetic protocols leading to gold-aryl compounds bearing...
For the past dozen years, homogeneous gold catalysis has evolved from a little known topic in organi...
Recently established as an excellent activator for π-systems, efforts made in gold chemistry have in...
In Chapter 2, a gold-catalyzed domino annulation of diazo-tethered alkynes with nitriles proceeds th...
<p><p>The wide-spread occurrence of biologically active nitrogen-containing heterocycles and allylic...
A novel gold-catalyzed water-mediated carbene cascade reaction of propargyl diazoacetates has been d...
none6noThe site-selective a-allylic alkylation of enones with alcohols via gold-triggered formation ...
The advent of gold catalysis has transformed hydroxyalkoxylation of alkynes - once a rudimentary, me...
DoctorThe addition reaction to a carbon-carbon multiple bond in a catalytic version is one of the mo...