The monodisperse pore structure of MOFs (metal–organic frameworks) is advantageous for investigating how porosity influences diffusion. Here we report translational and rotational diffusion using fluorescence correlation spectroscopy and time-correlated single-photon counting, using the three-dimensional pores of the zeolitic-like metal–organic framework family. We compare the influence of size and electric charge as well as dependence on pore size that we controlled through postsynthetic cation-exchange modifications. Charge–charge interactions with the MOF appeared to produce transient adsorption, manifested as a relatively fast and a slower diffusion process, but diffusants without net electric charge displayed a single diffusion process...
Diffusion is an omnipresent, most fundamental phenomenon in nature and thus critical for the perform...
Metal–organic frameworks are promising materials for energy-efficient gas separations, but little is...
Guest transport through metal–organic frameworks (MOFs) is a critical process in the application of ...
The monodisperse pore structure of MOFs (metal–organic frameworks) is advantageous for investigating...
The monodisperse pore structure of MOFs (metal-organic frameworks) is advantageous for investigating...
Nanoporous solids are ubiquitous in chemical, energy, and environmental processes, where controlled ...
The design and development of many emerging separation and catalytic process technologies require a ...
Investigation of guest diffusion in porous metal–organic frameworks (MOFs) is of major importance, b...
The primary objective of this article is to investigate the relative influences of molecular dimensi...
The primary objective of this article is to investigate the relative influences of molecular dimensi...
Metal–organic frameworks (MOFs) possess characteristics, such as tunable pore size and chemical func...
The rapid diffusion of molecules in porous materials is critical for numerous applications including...
Published experimental data, underpinned by molecular simulations, are used to highlight the strong ...
Diffusion is an omnipresent phenomenon in nature. In the world of molecules, it describes their irre...
We used single-molecule fluorescence microscopy to study self-diffusion of a feedstock-like probe mo...
Diffusion is an omnipresent, most fundamental phenomenon in nature and thus critical for the perform...
Metal–organic frameworks are promising materials for energy-efficient gas separations, but little is...
Guest transport through metal–organic frameworks (MOFs) is a critical process in the application of ...
The monodisperse pore structure of MOFs (metal–organic frameworks) is advantageous for investigating...
The monodisperse pore structure of MOFs (metal-organic frameworks) is advantageous for investigating...
Nanoporous solids are ubiquitous in chemical, energy, and environmental processes, where controlled ...
The design and development of many emerging separation and catalytic process technologies require a ...
Investigation of guest diffusion in porous metal–organic frameworks (MOFs) is of major importance, b...
The primary objective of this article is to investigate the relative influences of molecular dimensi...
The primary objective of this article is to investigate the relative influences of molecular dimensi...
Metal–organic frameworks (MOFs) possess characteristics, such as tunable pore size and chemical func...
The rapid diffusion of molecules in porous materials is critical for numerous applications including...
Published experimental data, underpinned by molecular simulations, are used to highlight the strong ...
Diffusion is an omnipresent phenomenon in nature. In the world of molecules, it describes their irre...
We used single-molecule fluorescence microscopy to study self-diffusion of a feedstock-like probe mo...
Diffusion is an omnipresent, most fundamental phenomenon in nature and thus critical for the perform...
Metal–organic frameworks are promising materials for energy-efficient gas separations, but little is...
Guest transport through metal–organic frameworks (MOFs) is a critical process in the application of ...