Transition‐Metal‐Catalysed Reactions of Diazoesters. Insertion into C‐H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C‐H Bonds

Demonceau, Albert
Noels, Alfred
Hubert, André J.
Teyssié, Philippe

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Publication date

January 1984

DOI

10.1002/bscb.19840931103

Publisher

Wiley

Abstract

peer reviewedRhodium(II) carboxylates associated with bulky ligands catalyse the insertion of carbalkoxycarbenes (generated from diszoesters) into C‐H bonds of normal and branched alkanes with selectivities differing substantially from those associated with non‐bulky carboxylates. Copyright © 1984 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinhei

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Transition‐Metal‐Catalysed Reactions of Diazoesters. Insertion into C‐H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C‐H Bonds

Abstract

Extracted data

Transition‐Metal‐Catalysed Reactions of Diazoesters. Insertion into C‐H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C‐H Bonds

Abstract

Extracted data

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