In our companion paper, we described the preparation and intercalation of two homologous series of dicarbonyl compounds, methyl n-oxooctadecanoates and the corresponding n-oxooctadecanoic acids (n = 4–16), into DMPC liposomes. 13C NMR chemical shift of the various carbonyls was analyzed using an ET(30) solvent polarity–chemical shift correlation table and the corresponding calculated penetration depth (in Å). An iterative best fit analysis of the data points revealed an exponential correlation between ET(30) micropolarity and the penetration depth (in Å) into the liposomal bilayer. However, this study is still incomplete, since the plot lacks data points in the important area of moderately polarity, i.e., in the ET(30) range of 51–45.5 kcal...
Deuterium wide line NMR spectroscopy was used to study cholesterol effects on the ceramide portions ...
The self-assembled supramolecular structures of diacylphosphatidylcholine (diCnPC), diacylphosphatid...
The position on a subnanometer scale and the dynamics of structurally important water in model membr...
The development of “molecular rulers” would allow one to quantitatively locate the penetration depth...
Afri et al., 2014a, Afri et al., 2014b have recently reported their mapping of DMPC liposomes using ...
In previous work, we have been able to determine the depth of intercalated molecules within the lipi...
The interaction of eight n-alkanols with bilayers of dimyristoylphosphatidylcholine (DMPC) has been ...
[[abstract]]13C-NMR spectra have been obtained at 50.3 MHz for monoarachidoylphosphatidylcholine (MA...
We introduce a new NMR technique to dramatically enhance the solution-state 13C NMR sensitivity and ...
Multinuclear solid state MAS NMR (1H and 31P), 31P CSA solid state NMR, 2H NMR and x-ray diffraction...
With molecular dynamics simulations of phospholipid membranes becoming a reality, there is a growing...
2H-NMR measurements of the ordering of several n-alkane and one n-alcohol solutes in lipid bilayers ...
AbstractWe report a simple new nuclear magnetic resonance (NMR) spectroscopic method to investigate ...
AbstractInvestigations of lipid membranes using NMR spectroscopy generally require isotopic labeling...
The role of lipid diversity in biomembranes is one of the major unsolved problems in biochemistry. O...
Deuterium wide line NMR spectroscopy was used to study cholesterol effects on the ceramide portions ...
The self-assembled supramolecular structures of diacylphosphatidylcholine (diCnPC), diacylphosphatid...
The position on a subnanometer scale and the dynamics of structurally important water in model membr...
The development of “molecular rulers” would allow one to quantitatively locate the penetration depth...
Afri et al., 2014a, Afri et al., 2014b have recently reported their mapping of DMPC liposomes using ...
In previous work, we have been able to determine the depth of intercalated molecules within the lipi...
The interaction of eight n-alkanols with bilayers of dimyristoylphosphatidylcholine (DMPC) has been ...
[[abstract]]13C-NMR spectra have been obtained at 50.3 MHz for monoarachidoylphosphatidylcholine (MA...
We introduce a new NMR technique to dramatically enhance the solution-state 13C NMR sensitivity and ...
Multinuclear solid state MAS NMR (1H and 31P), 31P CSA solid state NMR, 2H NMR and x-ray diffraction...
With molecular dynamics simulations of phospholipid membranes becoming a reality, there is a growing...
2H-NMR measurements of the ordering of several n-alkane and one n-alcohol solutes in lipid bilayers ...
AbstractWe report a simple new nuclear magnetic resonance (NMR) spectroscopic method to investigate ...
AbstractInvestigations of lipid membranes using NMR spectroscopy generally require isotopic labeling...
The role of lipid diversity in biomembranes is one of the major unsolved problems in biochemistry. O...
Deuterium wide line NMR spectroscopy was used to study cholesterol effects on the ceramide portions ...
The self-assembled supramolecular structures of diacylphosphatidylcholine (diCnPC), diacylphosphatid...
The position on a subnanometer scale and the dynamics of structurally important water in model membr...