The purpose of the work described in this thesis was the synthesis of a new class of surfactants containing chiral cationic end groups and the synthesis of two chiral reactant molecules which would react in the presence of these surfactants. The structures of the surfactant and substrate molecules were designed to maximize their stereochemical interactions and in this way reveal details of the nature of micellar catalysis. In order to indicate why these structures were selected, several examples of micellar catalysis and the factors influencing it will be discussed in the following pages
The development of micellar catalysis offers a sustainable alternative to organic solvents represent...
Phase-transfer catalysis has been recognized as a powerful and green sustainable method for organic ...
We have recently introduced a new class of chiral ammonium salt catalysts derived from easily availa...
The purpose of the work described in this thesis was the synthesis of a new class of surfactants con...
A general synthetic method for the synthesis of a new class of chiral surfactants with reactive OH g...
Aqueous micellar systems proved to be an excellent reaction medium for the selective synthesis of bi...
A convenient procedure for the synthesis of bis-quaternary ammonium salts from long-chain alkyldimet...
Three series of new oligomeric cationic surfactants were synthesized. These amphiphiles are trimeric...
International audienceThis personal account summarizes our contribution to the ion pairing organocat...
Three series of new oligomeric cationic surfactants were synthesized. These amphiphiles are trimeric...
A novel strategy for highly efficient utilization of chiral ammonium salt catalysts has been describ...
This thesis explores physical autocatalysis, or the replication of supramolecular aggregates of surf...
A number of synthetic approaches to preparing a metal-binding surfactant, containing the α-dio...
Chiral phase-transfer catalysis provides high level of enantiocontrol, however no experimental data ...
Micelles can affect the rate, stereo-, regio- and enantioselectivity of organic reactions. ¹²³ This ...
The development of micellar catalysis offers a sustainable alternative to organic solvents represent...
Phase-transfer catalysis has been recognized as a powerful and green sustainable method for organic ...
We have recently introduced a new class of chiral ammonium salt catalysts derived from easily availa...
The purpose of the work described in this thesis was the synthesis of a new class of surfactants con...
A general synthetic method for the synthesis of a new class of chiral surfactants with reactive OH g...
Aqueous micellar systems proved to be an excellent reaction medium for the selective synthesis of bi...
A convenient procedure for the synthesis of bis-quaternary ammonium salts from long-chain alkyldimet...
Three series of new oligomeric cationic surfactants were synthesized. These amphiphiles are trimeric...
International audienceThis personal account summarizes our contribution to the ion pairing organocat...
Three series of new oligomeric cationic surfactants were synthesized. These amphiphiles are trimeric...
A novel strategy for highly efficient utilization of chiral ammonium salt catalysts has been describ...
This thesis explores physical autocatalysis, or the replication of supramolecular aggregates of surf...
A number of synthetic approaches to preparing a metal-binding surfactant, containing the α-dio...
Chiral phase-transfer catalysis provides high level of enantiocontrol, however no experimental data ...
Micelles can affect the rate, stereo-, regio- and enantioselectivity of organic reactions. ¹²³ This ...
The development of micellar catalysis offers a sustainable alternative to organic solvents represent...
Phase-transfer catalysis has been recognized as a powerful and green sustainable method for organic ...
We have recently introduced a new class of chiral ammonium salt catalysts derived from easily availa...