Disequilibrium Dihedral Angles in Layered Intrusions: a Microstructural Record of Fractionation

The dihedral angle formed at junctions between two plagioclase grains and a grain of augite is only very rarely in textural equilibrium in gabbros from kilometre-scale crustal layered intrusions. The median of a population of these disequilibrium angles, θcpp, varies systematically within a single layered intrusion, remaining constant over large stretches of stratigraphy with significant increases and decreases associated with the addition orircled dash}cpp are present in the Upper Zone of the Bushveld Complex, the Megacyclic Unit I of the Sept Iles Intrusion, and the Layered Series of the Skaergaard intrusion.The plagioclase-bearing cumulate reduction respectively of the number of phases on the liquidus of the bulk magma.The stepwise changes in {cs of Rum have a bimodal distribution of {circled dash}cpp, dependent on whether the cumulus assemblage includes clinopyroxene.The presence of the stepwise changes is independent of the order of arrival of cumulus phases and of the composition of either the cumulus phases or the inferred composition of the interstitial liquid.The only parameter that behaves in an exactly analogous manner to Ycpp is the rate of change in enthalpy with temperature ({rectangle openH/{rectangle openT) during crystallization. Both {rectangle openH/{rectangle openTand {circled dash}cpp increase with the addition of a liquidus phase, and decrease with the removal of a liquidus phase. The replacement of one phase by another has little effect on {rectangle openH/{rectangle openTand no discernible effect on {circled dash}cpp. An increase of {rectangle openH/{rectangle openT results in an increase in the fraction of the total enthalpy budget that is the latent heat of crystallization (the fractional latent heat). It also increases the mass crystallized in each incremental temperature drop (the crystal productivity). These increases of both fractional latent heat and crystal productivity are likely to cause an increase in the time taken to form three-grain junctions in the mush via thermal buffering of a thickened mushy layer.We suggest these are the underlying causes of stepwise increases in {circled dash}cpp. Stepwise changes in the geometry of three-grain junctions in fully solidified gabbros thus provide a clear microstructural marker for the progress of fractionation down the liquid line of descent in layered intrusions. © The Author 2013. Published by Oxford University Press.status: publishe