Triplet energy management between two signaling units through cooperative rigid scaffolds

[EN] Through-bond triplet exciplex formation in donor-acceptor systems linked through a rigid bile acid scaffold has been demonstrated on the basis of kinetic evidence upon population of the triplet acceptors (naphthalene, or biphenyl) by through-bond triplet-triplet energy transfer from benzophenone.Financial support from the Spanish Government (Grants SEV-2012-0267, CTQ2012-38754-C03-03, CTQ2013-47872-C2-1-P and JCI-2011-09926), EU (PCIG12GA-2012-334257), Generalitat Valenciana (Prometeo Program), and Technical University of Valencia (VLC/Campus, ASIC-UPV for computational facilities and Predoctoral FPI fellowship for P. Miro) is gratefully acknowledged.Miró Richart, P.; Vayá Pérez, I.; Sastre Navarro, GI.; Jiménez Molero, MC.; Marín García, ML.; Miranda Alonso, MÁ. (2016). Triplet energy management between two signaling units through cooperative rigid scaffolds. Chemical Communications. 52(4):713-716. https://doi.org/10.1039/c5cc08102e71371652