Food aroma mass transport properties in renewable hydrophilic polymers

[EN] The sorption and transport properties of gliadin and chitosan films with respect to four representative food aroma components (ethyl caproate, 1-hexanol, 2-nonanone and α-pinene) have been studied under dry and wet environmental conditions. The partition coefficients (K) of the selected volatiles were also obtained using isooctane and soybean oil as fatty food simulants. The results showed that gliadin and chitosan films have very low capacities for the sorption of volatile compounds, and these capacities are influenced by the nature of the sorbate, the environmental relative humidity and the presence of glycerol as a plasticizer in the polymeric matrix. The volatile compounds also present a low partitioning in the biopolymer film/food stimulant system. Given the low levels of interaction observed with the volatiles, gliadin and chitosan films are of potential interest for the packaging of foods in which aroma is one of the most important quality attributes Highlights ► Sorption kinetics and equilibrium partitioning of food aroma compounds in bioplastics. ► Gliadin and chitosan films show low sorption and partitioning capacities of food aroma compounds. ► Sorption and diffusion depend on volatile chemical structure, film composition and moisture. ► Great potential in packaging of foods in which aroma is an important quality attribute.This research has been supported from the Spanish Ministry of Science and Innovation through the Projects AGL2006-02176, AGL2009-08776 and FUN-C-FOOD Consolider Ingenio. The authors would like to thank A.P. Mac Cabe for critical reading of the manuscript.Balaguer, MP.; Gavara Clemente, R.; Hernández Muñoz, P. (2012). Food aroma mass transport properties in renewable hydrophilic polymers. Food Chemistry. 130(4):814-820. https://doi.org/10.1016/j.foodchem.2011.07.052814820130