Gold-copper nanoalloys supported on TiO2 as photocatalysts for CO2 reduction by water

Commercial P25 modified by AuCu alloy nanoparticles as thin film exhibits, for CO2 reduction by water under sun simulated light, a rate of methane production above 2000 mu mol (g of photocatalyst)(-1) h(1). Although evolution of hydrogen is observed and O-2 and ethane detected, the selectivity of conduction band electrons for methane formation is almost complete, about 97%. This photocatalytic behavior is completely different from that measured for Au/P25 (hydrogen evolution) and Cu/P25 (lower activity, but similar methane selectivity). Characterization by TEM, XPS, and UVvis spectroscopy shows that Au and Cu are alloyed in the nanoparticles. FT-IR spectroscopy and chemical analysis have allowed one to detect on the photocatalyst surface the presence of CO2 center dot-, CuCO, and elemental C. Accordingly, a mechanism in which the role of Au is to respond under visible light and Cu binds to CO and directs the reduction pathway is proposed.This work has been supported by the Marie Curie project PIEF-GA-2011-298740. Financial support by the Spanish Ministry of Economy and Competitiveness (Severo Ochoa CTQ 2012-32315) and the Generalidad Valenciana (Prometeo 2012/2013) is gratefully acknowledged. J.A.M.-A. acknowledges the assistance of the CSIC for their award of a Postdoctoral JAE-Doc contract.Neatu, S.; Maciá Agulló, JA.; Concepción Heydorn, P.; García Gómez, H. (2014). Gold-copper nanoalloys supported on TiO2 as photocatalysts for CO2 reduction by water. Journal of the American Chemical Society. 136(45):15969-15976. https://doi.org/10.1021/ja506433k15969159761364