We describe the postsynthetic modification of Zr-based metal organic frameworks (MOFs) containing chiral NNN-pincer ligands based on aminopyridineimines, as well as the subsequent formation of (NNN)-M-Zr-MOF complexes (M=Rh, Ir). With these new multifunctional materials, we performed a cascade of condensation reactions followed by hydrogenation of the resulting double bond. If the condensation reaction occurs between an aldehyde and ethyl nitroacetate, (NNN)-M-Zr-MOF complexes catalyze the one-pot synthesis of nitroalkenes, in which Zr-IV Lewis sites play a role similar to that of the generally used Ti-IV in homogeneous catalysis. These multifunctional hybrid catalysts retain their crystalline framework even after the reaction, and they wer...
[DE] Das Konzept der “festen Lösungen mit gemischten Linkern” (mixed-linker solid solution concept) ...
[EN] New zincocenes [ZnCp'2] (2-5) with substituted cyclopentadienyl ligands C(5)Me(4)H, C(5)Me(4)tB...
Layered hybrid materials (LHMs) based on ordered silicoaluminate sheets linked with organic fragment...
[EN] A bifunctional metal organic framework catalyst containing palladium and copper(II) benzene- 1,...
[EN] The present review describes the use of metal-organic frameworks (MOFs) as porous matrices to e...
"This document is the Accepted Manuscript version of a Published Work that appeared in final form in...
[EN] Isophthalic acid (IPA) has been considered to build metal-organic frameworks (MOFs), owing to i...
[EN] In the present work, nitro functionalized chromium terephthalate [MIL-101(Cr)-NO2] metal-organi...
[EN] This work reports the synthesis of pyridyltriazol-functionalized UiO-66 (UiO stands for Univers...
[EN] Metal organic frameworks (MOFs) are being intensively studied as solid catalysts for organic re...
[EN] Organic inorganic hybrid materials with different levels of structuration and porous hierarchy ...
[EN] The novel homochiral metal-organic framework CFA-1 (Coordination Framework Augsburg-1), [Zn-5(O...
[EN] The direct N-alkylation of amines with alcohols was performed with an Ir-Zr-based metal-organic...
[EN] The cationic complex [(JohnPhos-Au)(3)(acetylide)][SbF6] (JohnPhos=(2-biphenyl)di-tert-butylpho...
[EN] Hf-based metal-organic frameworks (MOFs) are reported here as heterogeneous catalysts for the h...
[DE] Das Konzept der “festen Lösungen mit gemischten Linkern” (mixed-linker solid solution concept) ...
[EN] New zincocenes [ZnCp'2] (2-5) with substituted cyclopentadienyl ligands C(5)Me(4)H, C(5)Me(4)tB...
Layered hybrid materials (LHMs) based on ordered silicoaluminate sheets linked with organic fragment...
[EN] A bifunctional metal organic framework catalyst containing palladium and copper(II) benzene- 1,...
[EN] The present review describes the use of metal-organic frameworks (MOFs) as porous matrices to e...
"This document is the Accepted Manuscript version of a Published Work that appeared in final form in...
[EN] Isophthalic acid (IPA) has been considered to build metal-organic frameworks (MOFs), owing to i...
[EN] In the present work, nitro functionalized chromium terephthalate [MIL-101(Cr)-NO2] metal-organi...
[EN] This work reports the synthesis of pyridyltriazol-functionalized UiO-66 (UiO stands for Univers...
[EN] Metal organic frameworks (MOFs) are being intensively studied as solid catalysts for organic re...
[EN] Organic inorganic hybrid materials with different levels of structuration and porous hierarchy ...
[EN] The novel homochiral metal-organic framework CFA-1 (Coordination Framework Augsburg-1), [Zn-5(O...
[EN] The direct N-alkylation of amines with alcohols was performed with an Ir-Zr-based metal-organic...
[EN] The cationic complex [(JohnPhos-Au)(3)(acetylide)][SbF6] (JohnPhos=(2-biphenyl)di-tert-butylpho...
[EN] Hf-based metal-organic frameworks (MOFs) are reported here as heterogeneous catalysts for the h...
[DE] Das Konzept der “festen Lösungen mit gemischten Linkern” (mixed-linker solid solution concept) ...
[EN] New zincocenes [ZnCp'2] (2-5) with substituted cyclopentadienyl ligands C(5)Me(4)H, C(5)Me(4)tB...
Layered hybrid materials (LHMs) based on ordered silicoaluminate sheets linked with organic fragment...