A Synthesis of an Ionomycin Calcium Complex
- Gao, Zhangua
- Li, Yingfa
- Cooksey, John P
- Snaddon, Thomas N
- Schunk, Stefan
- Viseux, Eddy M E
- McAteer, Stephen M
- Kocienski, Philip J
DOIAbstract
A Synthesis of an Ionomycin Calcium Complex Caught in the middle : The ionomycin calcium complex (see structure ; O red, Ca green) was the target of an approach featuring the efficient asymmetric syn- thesis of an allene by a copper(I)-mediated anti-selective SN2 reaction, a highly stereoselective gold(III)-catalyzed cycloisomerization of an a-hydroxyallene, and a Rh-catalyzed rearrangement of an a-diazo-b-hydroxyketone
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